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Concept explainers
(a)
Interpretation:
The name has to be given for the reactant (
Concept Introduction:
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.
Prefix- Represents the substituent present in the molecule and its position in the root name.
Suffix- Denotes the presence of
Root word - Represents the longest continuous carbon skeleton of the organic molecule.
(b)
Interpretation:
The structure of the isomer has to be drawn and the name has to be given
Concept Introduction:
Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.
(c)
Interpretation:
The name of product is to be identified in reaction A.
Concept Introduction:
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.
Prefix- Represents the substituent present in the molecule and its position in the root name.
Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on
Root word - Represents the longest continuous carbon skeleton of the organic molecule.
(d)
Interpretation:
The name of product is to be identified in reaction B.
Concept Introduction:
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.
Prefix- Represents the substituent present in the molecule and its position in the root name.
Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on
Root word - Represents the longest continuous carbon skeleton of the organic molecule.
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Chapter 23 Solutions
Chemistry & Chemical Reactivity
- (1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amidearrow_forward1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.arrow_forward5. Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group: Name the functional group:arrow_forward
- a) Draw the four isomers of C5H12O that can be oxidized to an aldehyde. (b) Draw the three isomers of C5H12O that can be oxidized to a ketone. (c) Draw the isomers of C5H12O that cannot be easily oxidized to an aldehyde or ketone. (d) Name any isomer that is an alcohol.arrow_forward4. Write the formula and name for the product when cyclopentene reacts with (a) Cl2(b) HBr(c) H2, Pt (d) H2O, H+arrow_forward1. (a) Draw structures of the seven isomeric alkynes of formula C6H10 - (b) Give the IUPAC and derived name of each. (c) Indicate which ones will react with Ag' or Cu(NH3)2.arrow_forward
- Classify each of the following reactions as an addition, elimination, substitution, or rearrangement: (a) CH3Br + KOH → CH3OH + KBr(b) CH3CH2Br → H2C=CH2 + HBr(c) H2C=CH2 + H2 → CH3CH3arrow_forward7. The general formula for noncyclic alkenes is: (a) CH-2 (b) CH (c) CH2 (d) CH (e) CH,arrow_forwardName and draw a structural formula for the major product of each alkene addition reaction: CH S (a) CH₂C=CH₂ + HI →→→→ (b) CH 3 + HClarrow_forward
- 1.Name and draw the products of each reaction. (a) 3-methyl oct-2-ene + hydrochloric acid (b) 2-fluoro-2-phenyl butanoic acid + ethanol → 1arrow_forward4) Draw (skeletal) and name the product(s) of the following reactions. If there is a major product, label it as such. If the reaction cannot happen, indicate this. Hydration of cis-2-butene H₂SO,/H₂Oarrow_forwardWrite a complete chemical equation showing reactants, products, and catalysts needed(if any) for the following reaction and (2) Draw and name the organic compound found inevery reaction.(Use condensed structural formula) (A) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr(B) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide(C) Formation of Gilman reagent using isopropyl bromidearrow_forward
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