Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 6.7, Problem 11P
Interpretation Introduction
Interpretation:
Among the two reactions, one with Keq=1000 and other with Keq=0.001, which is likely to be more exergonic is to be stated.
Concept introduction:
When ΔG0 is negative, the reaction is exergonic, has a favorable equilibrium constant and occurs spontaneously. When ΔG0 is positive, the reaction is endergonic, has an unfavorable equilibrium constant and cannot occur spontaneously.
To state:
Among the two reactions, one with Keq=1000 and other with Keq=0.001, which is likely to be more exergonic.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Calculate the energy change of the following reaction:
2NO + O2→ 2NO2
ΔH:
NO = 90.0 kJ/mol
NO2= 34.0 kJ/mol
O2= 0.0 kJ/mol
a
-180 kJ
b
-112 kJ
c
35.0 kJ
d
-248 kJ
1) Which reaction is likely to be more exergonic, one with Keq = 1000 or one with Keq = 0.001?
Using the table of average bond dissociation enthalpies at 25°C, determine which of the following reactions are energetically favorable at room temperature. Assume that ▲S = 0.
Q. CH2=CH2 + CHI3 --> CH3CH2CI3
Chapter 6 Solutions
Organic Chemistry
Ch. 6.1 - Prob. 1PCh. 6.3 - Prob. 2PCh. 6.3 - Using curved fishhook arrows, propose a mechanism...Ch. 6.4 - Prob. 4PCh. 6.4 - An electrostatic potential map of boron...Ch. 6.5 - What product would you expect from reaction of...Ch. 6.5 - Reaction of HBr with 2-methylpropene yields...Ch. 6.6 - Prob. 8PCh. 6.6 - Predict the products of the following polar...Ch. 6.7 - Which reaction is more energetically favored, one...
Ch. 6.7 - Prob. 11PCh. 6.9 - Which reaction is faster, one with ∆G‡ = +45...Ch. 6.10 - Prob. 13PCh. 6.SE - Prob. 14VCCh. 6.SE - Prob. 15VCCh. 6.SE - Prob. 16VCCh. 6.SE - Look at the following energy diagram: (a) Is...Ch. 6.SE - Look at the following energy diagram for an...Ch. 6.SE - What is the difference between a transition state...Ch. 6.SE - Prob. 20EDRMCh. 6.SE - Prob. 21EDRMCh. 6.SE - Draw an energy diagram for a two-step exergonic...Ch. 6.SE - Draw an energy diagram for a reaction with keq =...Ch. 6.SE - The addition of water to ethylene to yield ethanol...Ch. 6.SE - When isopropylidenecyclohexane is treated with...Ch. 6.SE - Prob. 26EDRMCh. 6.SE - Draw the electron-pushing mechanism for each...Ch. 6.SE - Draw the complete mechanism for each polar...Ch. 6.SE - Prob. 29EDRMCh. 6.SE - Identify the functional groups in the following...Ch. 6.SE - Identify the following reactions as additions,...Ch. 6.SE - Identify the likely electrophilic and nucleophilic...Ch. 6.SE - For each reaction below identify the electrophile...Ch. 6.SE - Prob. 34APCh. 6.SE - Follow the flow of electrons indicated by the...Ch. 6.SE - Prob. 36APCh. 6.SE - Prob. 37APCh. 6.SE - Despite the limitations of radical chlorination of...Ch. 6.SE - Prob. 39APCh. 6.SE - Answer question 6-39 taking all stereoisomers into...Ch. 6.SE - Prob. 41APCh. 6.SE - Prob. 42APCh. 6.SE - Prob. 43APCh. 6.SE - The reaction of hydroxide ion with chloromethane...Ch. 6.SE - Prob. 45APCh. 6.SE - Ammonia reacts with acetyl chloride (CH3COCl) to...Ch. 6.SE - The naturally occurring molecule α-terpineol is...Ch. 6.SE - Prob. 48APCh. 6.SE - Prob. 49APCh. 6.SE - Draw the structures of the two carbocation...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Acetic acid, CH3 COOH, is a weak organic acid, pK a 4.47. Determine the position of the equilibrium for the reaction of acetic acid with NaHCO3, and draw the species that predominate at equilibrium. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. •Separate structures with + signs from the drop-down menu. • Draw cations and anions in separate sketchers. Do not include metal counter-ions, e.g., Nat, in your answer. 0- ● [... / ? ChemDoodle Ⓡ Y Sn [Farrow_forwardPredict the product of the following organic reaction: CH₂ CH O || C–CH2–CH=CH—(CH2)3 CH3 (CH₂)3 CH=CH- - CH₂ CH3 + 4 H₂ Ni CH,−O -C–CH2–CH=CH–CH=CH–CH2–CH3 Specifically, in the drawing area below, draw the chemical structure of the product P. If there is no product, because this reaction won't happen, check the No reaction box under the drawing area. Click and drag to start drawing a structure. × Ś +arrow_forwardFor the following reactions, predict the likely product(s) of the reaction or write 'no reaction." Me H Me °x Me Me Me Br Me Me Me Nal, NaOCI EtOH, H₂O HNO3 ACOH AICI 3arrow_forward
- Did you first add the H2O(l) on the right side of the equaton and then added the 2HO- on the left side and multiplied CIO2 on the left side by 2?arrow_forwardUsing the appropriate bond energies, calculate the heat of reaction AH for the following reaction: H | H | 2H C H + 30=0 2C=0 + 40-H H You can find a table of bond energies by using the Data button on the ALEKS toolbar. Round your answer to the nearest kJ/mol. Note: For clarity, all lone pairs have been omitted from the molecular structures. kJ mol Хarrow_forwardWhich value (if any) corresponds to a faster reaction: (a) Ea = 40 kJ/mol or Ea = 4 kJ/mol;(b) a reaction temperature of 0 °C or a reaction temperature of 25 °C; (c) Keq = 10 or Keq = 100; (d) ΔHo = −10 kJ/mol or ΔHo = 10 kJ/mol?arrow_forward
- Which value (if any) corresponds to a faster reaction: (a) Ea = 40 kJ/mol or Ea = 4 kJ/mol; (b) a reaction temperature of 0 °C or a reaction temperature of 25 °C; (c) Keq = 10 or Keq = 100; (d) ΔHo = −10 kJ/mol or ΔHo = 10 kJ/mol?arrow_forwardGiven the following reactions 2NO → N2 + O2 ΔH = -180 kJ 2NO + O2 → 2NO2 ΔH = -112 kJarrow_forwardно LOH он HCI (aq.) но- G+H +I но но. heat OH ÓMe но но H', CH3OH но- но. K (major product) онarrow_forward
- Draw the orgamic molecule(s) which is(are) formed in the following reaction. Do not include molecules like H20 or HCl. (You have 2 chances until the answer will be given; you have already tried 0 times) он H, CH K2Cr,O,/ H* H,C CH C H, H,arrow_forwardUsing the table of average bond dissociation enthalpies at 25°C, determine which of the following reactions are energetically favorable at room temperature. Assume that ▲S = 0. Q.CH2=CH2 + 2H2 + N2 --> H2NCH2CH2NH2arrow_forwardAdentity the productis) of the following reaction. 1. KMO,/N/heal 2 HO • 2 CO COOH COOH 2 CO2 CO2 COOH OHarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning