Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Textbook Question
Chapter 26.4, Problem 9P
Draw the structure of M-P-V-G, and indicate its amide bonds.
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Draw all the possible amide isomers with C3H7NO molecular formula.
OH
Amide
H-C-0 H
100
(C)
(a)
Draw the skeletal ("line") structure of a secondary amine with 4 carbon atoms, and no double or triple bonds.
Chapter 26 Solutions
Organic Chemistry
Ch. 26.1 - How many of the -amino acids shown in Table 26-1...Ch. 26.1 - Prob. 2PCh. 26.1 - Prob. 3PCh. 26.2 - Hemoglobin has pI=6.8. Does hemoglobin have a net...Ch. 26.3 - Show how you could prepare the following -amino...Ch. 26.3 - What alkyl halides would you use to prepare the...Ch. 26.3 - Prob. 7PCh. 26.4 - There are six isomeric tripeptides that contain...Ch. 26.4 - Draw the structure of M-P-V-G, and indicate its...Ch. 26.5 - Prob. 10P
Ch. 26.5 - Prob. 11PCh. 26.6 - The octapeptide angiotensin II has the sequence...Ch. 26.6 - Prob. 13PCh. 26.6 - Prob. 14PCh. 26.6 - Give the amino acid sequence of hexapeptides that...Ch. 26.7 - Prob. 16PCh. 26.7 - Write all five steps required for the synthesis of...Ch. 26.10 - Prob. 18PCh. 26.SE - Identify the following amino acids:Ch. 26.SE - Prob. 20VCCh. 26.SE - Isoleucine and threonine are the only two amino...Ch. 26.SE - Prob. 22VCCh. 26.SE - Give the sequence of the following tetrapeptide:Ch. 26.SE - Prob. 24MPCh. 26.SE - The chloromethylated polystyrene resin used for...Ch. 26.SE - Prob. 26MPCh. 26.SE - Prob. 27MPCh. 26.SE - Prob. 28MPCh. 26.SE - Except for cysteine, only S amino acids occur in...Ch. 26.SE - Prob. 30APCh. 26.SE - Prob. 31APCh. 26.SE - Show the structures of the following amino acids...Ch. 26.SE - Prob. 33APCh. 26.SE - Using both three- and one-letter codes for amino...Ch. 26.SE - Prob. 35APCh. 26.SE - Show how you could use the acetamidomalonate...Ch. 26.SE - Prob. 37APCh. 26.SE - Show how you could prepare the following amino...Ch. 26.SE - Prob. 39APCh. 26.SE - Predict the product of the reaction of valine with...Ch. 26.SE - Prob. 41APCh. 26.SE - Prob. 42APCh. 26.SE - Propose two structures for a tripeptide that gives...Ch. 26.SE - Show the steps involved in a synthesis of...Ch. 26.SE - Prob. 45APCh. 26.SE - Prob. 46APCh. 26.SE - Prob. 47APCh. 26.SE - Which of the following amino acids are more likely...Ch. 26.SE - Leuprolide is a synthetic nonapeptide used to...Ch. 26.SE - The -helical parts of myoglobin and other proteins...Ch. 26.SE - Prob. 51APCh. 26.SE - Cytochrome c is an enzyme found in the cells of...Ch. 26.SE - Prob. 53APCh. 26.SE - Prob. 54APCh. 26.SE - Prob. 55APCh. 26.SE - What is the structure of a nonapeptide that gives...Ch. 26.SE - Oxytocin, a nonapeptide hormone secreted by the...Ch. 26.SE - Aspartame, a nonnutritive sweetener marketed under...Ch. 26.SE - Prob. 59APCh. 26.SE - Prob. 60APCh. 26.SE - Prob. 61APCh. 26.SE - Prob. 62AP
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- What is the meaning of the term tertiary (3) when it is used to classify amines? Draw a structural formula for the one tertiary (3) amine known as Hnigs base (N,N-diisopropylethylamine).arrow_forwardThe structure of an amide is shown below. || -C - NHCH,CH3 An amide can be reduced to an amine when treated with a reducing agent. Give the class type of the amine formed. Answer:arrow_forwardThe C-N distance in an amide bond is approximately 1.32 Å. A typical C-N single bond is 1.45Å, while a typical C=N double bond is 1.25 Å. Explain this observation and describe how thebonding in amides restricts the conformations amides can adopt.arrow_forward
- Explain why it is impossible to form an amide by the condensation of a tertiary amine with a carboxylic acid.arrow_forwarddraw 2 isomers tertiary amine with the formula C5H13Narrow_forward22. How will you name this compound: 3HC-CH2-CH2-CH2-CH2-CH2- NH2? O hexanol amide O hexyl amide O hexyl aminearrow_forward
- 1. very brief explanation Choose the letter of the best answer to each question below and provide a Which of the following compounds is called an amide? I of & NH₂ NH HO A B с D Earrow_forwardBecause amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forwardTertiary amides have how many C-N bonds?arrow_forward
- Consider the structure of bupropion hydrochloride. H H V C1 Draw the structure of the amine that reacts with HC1 to generate bupropion hydrochloride.arrow_forwardThe amide formed in the reaction of benzoic acid and ethylamine is CH,NHCH2CH3 CNHCH CH3 ONHCH,CH3 NHCCH,arrow_forwardDraw the condensed structure of a secondary amide with 4 carbon atoms.arrow_forward
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