A solution of Ba (OH), was standardized against 0.1208 g of primary-standard-grade benzoic acid, C6H5 COOH (122.12 g/mol). An end point was observed after addition of 43.94 mL of base. a. Calculate the molar concentration of the base. Concentration =| M b. Calculate the standard deviation of the molar concentration if the standard deviation for the mass measurement was +0.4 mg and that for the volume measurement was +0.02 mL. Standard deviation = M c. Assuming an error of -0.3 mg in the mass measurement, calculate the absolute and relative systematic error in the molar concentration.

A solution of Ba (OH), was standardized against 0.1208 g of primary-standard-grade benzoic acid, C6H5 COOH (122.12 g/mol). An end point was observed after addition of 43.94 mL of base. a. Calculate the molar concentration of the base. Concentration =| M b. Calculate the standard deviation of the molar concentration if the standard deviation for the mass measurement was +0.4 mg and that for the volume measurement was +0.02 mL. Standard deviation = M c. Assuming an error of -0.3 mg in the mass measurement, calculate the absolute and relative systematic error in the molar concentration.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter16: Applications Of Neutralization Titrations

Section: Chapter Questions

Problem 16.18QAP

See similar textbooks

Similar questions

1. A student performed this experiment and obtained the following concentration values: 0.02813 M, 0.02802, and 0.02788 M a. what is the mean concentration? b. what is the standard deviation of these results? 3. how would the following errors affect the concentration of Cl- obtained in question 2b? give your reasoning in each case. a. the student read the molarity of AgNo3 as 0.02104M instead of 0.02014M b. the student was past the endpoint of titration when he took the final buret reading.
For EACH type of gravimetric analysis:Give actual applications of each analysis. Include the SPECIFIC methodology for each sample chosen.
A solution of Ba(OH)2 was standardized against0.1215 g of primary-standard-grade benzoic acid, C6H5COOH (122.12 g/mol). An end point was observedafter addition of 43.25 mL of base. (a) Calculate the molar concentration of the base. (b) Calculate the standard deviation of the molarconcentration if the standard deviation for themass measurement was ±0.3 mg and that for thevolume measurement was ±0.02 mL. (c) Assuming an error of ±0.3 mg in the mass measurement,calculate the absolute and relative systematicerror in the molar concentration.
A titrimetric method for the determination of calcium in limestone was tested by analysis of an NIST limestone containing 30.15% CaO. The mean result of four analyses was 30.26% CaO, with a standard deviation of 0.085%. By pooling data from several analyses, it was established that s   = 0.094% CaO.a. Do the data indicate the presence of a systematic error at the 95% confidence level?b. Do the data indicate the presence of systematic error at the 95% confidence level if no pooled value for s was available?
A 0.1475-M solution of Ba(OH)2 was used to titrate the acetic acid (60.05 g/mol) in a dilute aqueous solution. The following results were obtained. (See attached image)(a) Calculate the mean w/v percentage of acetic acid in the sample.(b) Calculate the standard deviation for the results.(c) Calculate the 90% confidence interval for the mean.(d) (d) At the 90% confidence level, could any of the results be discarded?
In a volumetric determination of an analyte A, the data obtained and their standard deviations are as follows: Initial buret reading 0.19 mL 0.02 mL Final buret reading 7.86 mL 0.03 mL Sample mass 63.0 mg 0.2 mg From the data, find the coefficient of variation of the final result for the %A that is obtained by using the equation that follows and assuming there is no uncertainty in the equivalent mass. %A= titrant volume x equivalent mass x 100 %/ sample mass Coefficient of variation = Submit Answer % Try Another Version 10 item attempts remaining
7) The homogeneity of the chloride level in a water sample from a lake was tested by an analyst. Below are the concentration in parts per million (ppm) of Cl: 27.32, 27.22, 27.21, 27.24, 27.20 i. Determine the mean and median. ii. Calculate the confidence limit at 90%. iii. Identify a possible outlier and use the Q-test to determine whether it can be retained or rejected at 90% confidence level
A 0.1475-M solution of Ba(OH)2 was used to titrate the acetic acid (60.05 g/mol) in a dilute aqueous solution. The following results were obtained. (See attached image)(a) Calculate the mean w/v percentage of acetic acid in the sample.(b) Calculate the standard deviation for the results. (Take note if n-1 should be used)(c) Calculate the 90% confidence interval for the mean.(d) (d) At the 90% confidence level, could any of the results be discarded?
A volume of 250 ml of a 0.05 M solution of a reagent of formula weight (relative molecular mass) 40 was made up, the weighing being done by difference. The standard deviation of each weighing was 0.0001 g. The standard deviation of the volume of solvent used was 0.05 ml. Express this as a relative standard deviation. Hence calculate the relative standard deviation of the molarity of the solution.
00 mL of a diprotic acid primary standard solution was accurately prepared to a concentration of 0.1431 M. Three samples of this primary standard solution were used as samples in a titration to standardize an aqueous solution of sodium hydroxide, NaOH, which would be used as a titrant. Using the following table of data for the titration of the primary standard acid with NaOH, calculate the average concentration of NaOH. Trial # Volume of primary standard Initial titrant volume Final titrant volume 1 10.00 mL 8.21 mL 27.22 mL 2 10.00 mL 27.22 mL 46.23 mL 3 10.00 mL 30.28 mL 49.29 mL 0.1506 M 0.0753 M 0.0376 M 0.1431 M 0.0526 M
SCE students measured the concentration of HCl in a solution by titrating with different indicators to find the end point.Indicator Mean HCl concentration (M)(± standard deviation)Number of measurementsBromothymol blue 0.09565 ± 0.00225 28Methyl red 0.08686 ± 0.00098 18Bromocresol green 0.08641 ± 0.00113 29Is the difference between indicators 1 and 2 significant at the 95% confidence level? Answer the same question for indicators 2 and 3
A 15.00 g sample containing mixed alkali and other inert components was dissolved and diluted to 300 mL with water. A 20 mL aliquot was titrated with 5.02 mL of 0.5352 M HCl to reach PHP endpoint. Another 20 mL aliquot was titrated to the BCG endpoint, using up 18.87 mL of titrant in the process. Note: Answer in two decimal places only. If there is no answer, type in 0.00. Use the molar masses 105.989 ?/??l ??2cO3 and 84.007 g/mol NaHCO3 indicated. The volume of titrant needed to neutralize NaOH is _________ mL.The volume of titrant needed to neutralize Na2CO3 is _____________ mL.The volume of titrant needed to neutralize NaHCO3 is _____________ mL. The mass of NaOH is ___________ g.The mass of Na2CO3 is __________ g.The mass of NaHCO3 is __________ g. The percent weight of NaOH is __________ %.The percent weight of Na2CO3 is __________ %.The percent weight of NaHCO3 is __________ %.