Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 4E
Consider the incomplete orbital representation of
a. Identify which lobes are hybrid orbitals (identify the type) and which lobes arep orbitals.
b. Use dotted lines to show any
c. Use up or down arrows to show electron occupation of each hybrid orbital or bond.
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Students have asked these similar questions
1. Do all of the following for each molecule or ion.
a. Draw the Lewis Dot structure that minimizes
formal charges.
b. Draw the 3-D structure.
c. Determine the Hybridization designation of the
central atom.
d. Determine the VSEPR designation.
e. State what is its Molecular shape.
f. Determine whether it is Polar (P) or Nonpolar
(N).
A. SO3²-
B. CN-
C. BrF4+
D. IF5
E. SeO2
Answer the following questions about amoxicillin, an antibiotic from the penicillin family.
a. Predict the hybridization and geometry around each highlighted atom.
b. Label five polar bonds using the symbols δ+ and δ–.
c. How many π bonds does amoxicillin have? Label them.
d. Find a C – H bond containing a carbon atom having a hybrid orbital with 33% s-character
3. Label the hybridization of any lone pair below that is an p orbital and provide a rationale for its
hybridization.
a. Abacavir - nucleoside reverse transcriptase inhibitor (anti-viral) used for the treatment
of HIV/AIDS.
НО.
N
OH O
HN
b. Doxycycline - A broad spectrum antibiotic with more than 8 million prescriptions given
in the US every year.
OH O
OH||
'N
CH3 OH N
NH₂
OH
H3C CH3
NH₂
Chapter 3 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 3 - Prob. 1CTQCh. 3 - What neutral atom is represented by the electron...Ch. 3 - Prob. 3CTQCh. 3 - Consider any one of the four identical hybrid...Ch. 3 - Prob. 5CTQCh. 3 - Prob. 6CTQCh. 3 - Prob. 7CTQCh. 3 - Prob. 8CTQCh. 3 - Prob. 9CTQCh. 3 - Prob. 10CTQ
Ch. 3 - On the left side of Figure 3.6, label the areas...Ch. 3 - Prob. 12CTQCh. 3 - Prob. 13CTQCh. 3 - Prob. 14CTQCh. 3 - Prob. 15CTQCh. 3 - Now consider the fully formed molecule on the...Ch. 3 - Prob. 1ECh. 3 - Explain why the two molecules below cannot...Ch. 3 - Prob. 3ECh. 3 - Consider the incomplete orbital representation of...Ch. 3 - Consider the following orbital representation of...Ch. 3 - Summarize how one determines the hybridization...Ch. 3 - Explain what is wrong with each of the following...Ch. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Complete the following tables, and memorize their...Ch. 3 - Draw orbital representations of bonding in water...Ch. 3 - Draw electron configuration diagrams for carbon in...Ch. 3 - Prob. 13E
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- E. Write the functional groups present in the following compound. Group A Group C Br yo Group E Br H ago K. Identify the atomic orbitals that overlap to form the marked bonds and the bond type. -O-CH,CH, Group D Identify the hybridization and bond angle of the marked atoms. Br O-CH,CH2TN. M. CH₂CH3 CH₂CH3 Group E N. -O-CH,CH2−N CH₂CH3 CH₂CH3 CH₂CH3 CH₂CH3arrow_forwardAnswer the following questions about amoxicillin, an antibiotic from the penicillin family. NH2 H N. HO НО amoxicillin a. Predict the hybridization and geometry around each highlighted atom. b. Label five polar bonds using the symbols &+ and &–. C. How many r bonds does amoxicillin have? Label them. d. Find a C – H bond containing a carbon atom having a hybrid orbital with 33% s-character.arrow_forward18. What type of bonds hold organic molecules together? How are they different than the bonds that hold inorganic molecules together? Be specific, I want more than just names of bonds. 19. For the following molecule draw in all the dipole moments using 6+ and 6. XX 20. BONUS: Why can an sp² hybridized carbon not form a double bond? 7arrow_forward
- a. Using the molecular orbital diagram, calculate the bond order of F2+. Show show your work or give a brief explanation of the process. b. Do you expect this to have a shorter or longer bond length than F2? Explain your answer. c. Do you expect F2+ to be paramagnetic or diamagnetic? Explain your answer. Please label your answers a-c and place them on separate lines. Be as specific in your explanation as you can.arrow_forwardA. Which of the following statements is TRUE about the neutral nitrogen molecule, N2? Select one: . It is paramagnetic. . Its N–N bond length is shorter than that in the cationic nitrogen molecule ion. . Its calculated bond order is 2. . Its molecular orbital diagram shows that each nitrogen atom has two lone pairs. B. What is the correct complete molecular orbital notation for the N2 molecule? Select one: . σ1s² σ*1s² π2p⁴ σ*2p² . σ2s² σ*2s² π2p⁴ σ*2p² . σ1s² σ*1s² σ2s² σ*2s² π2p⁴ σ2p² . σ1s² σ*1s² σ2s² σ*2s² σ*2p² π2p⁴arrow_forward1. a) Sketch the Lewis structure and name the molecular VSEPR shape for CCl4 b) What is the hybridization for the C atoms in C2H2? Show your work. (Start with a Lewis structure. This molecule has a skeleton of HCCH.) c) Sketch an s orbital. (This is meant to be a simple question. Don't sweat it!) d) Sketch a p orbital of your choice. Indicate the phase and the cartesian directions (x, y, z axes).arrow_forward
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