The number of constitutional isomeric monohalogenated products that can form from butane should be determined. Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary. The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary. The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

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Answer 1

Question

Chapter 3, Problem 20P

(a) H

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from butane should be determined.

Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(b)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from pentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(c)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 3−methylpentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(d)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 1−methylcyclopentane should be determined.

Concept introduction: The carbon linked to one alkyl / carbon while other two H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl /carbons and one H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and no H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

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The energy difference between a tert-butyl group going from equatorial to axial in a cyclohexane is 18.3 kJ/mol. When two of the carbon atoms are replaced with oxygen atoms (molecule B) the energy difference between the two chair conformations drops to 5.9 kJ/mol. Explain this difference. (Hint: Consider what makes putting groups axial unfavorable).

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Answer 2

Question

Chapter 3, Problem 20P

(a) H

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from butane should be determined.

Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(b)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from pentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(c)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 3−methylpentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(d)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 1−methylcyclopentane should be determined.

Concept introduction: The carbon linked to one alkyl / carbon while other two H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl /carbons and one H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and no H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

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Answer 3

Question

Chapter 3, Problem 20P

(a) H

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from butane should be determined.

Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(b)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from pentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(c)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 3−methylpentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(d)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 1−methylcyclopentane should be determined.

Concept introduction: The carbon linked to one alkyl / carbon while other two H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl /carbons and one H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and no H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

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Answer 4

Question

Chapter 3, Problem 20P

(a) H

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from butane should be determined.

Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(b)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from pentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(c)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 3−methylpentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(d)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 1−methylcyclopentane should be determined.

Concept introduction: The carbon linked to one alkyl / carbon while other two H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl /carbons and one H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and no H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

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Answer 5

Chapter 3, Problem 20P

(a) H

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from butane should be determined.

Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(b)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from pentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(c)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 3−methylpentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

(d)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 1−methylcyclopentane should be determined.

Concept introduction: The carbon linked to one alkyl / carbon while other two H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl /carbons and one H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and no H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 6

Chapter 3, Problem 20P

(a) H

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from butane should be determined.

Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 7

Chapter 3, Problem 20P

(a) H

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from butane should be determined.

Concept introduction: The carbon linked to one alkyl/carbon while other three are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 8

(b)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from pentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 9

(b)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from pentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 10

(c)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 3−methylpentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 11

(c)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 3−methylpentane should be determined.

Concept introduction:The carbon linked to one alkyl/carbon while other three H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl/carbons and two H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and one H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 12

(d)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 1−methylcyclopentane should be determined.

Concept introduction: The carbon linked to one alkyl / carbon while other two H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl /carbons and one H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and no H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 13

(d)

Interpretation Introduction

Interpretation:The number of constitutional isomeric monohalogenated products that can form from 1−methylcyclopentane should be determined.

Concept introduction: The carbon linked to one alkyl / carbon while other two H are termed primary carbon. Thus, hydrogen linked to such carbon is referred as primary.

The carbon linked to two alkyl /carbons and one H is termed secondary carbon. Thus, hydrogen linked to such carbon is referred as secondary.

The carbon linked to three alkyl groups/carbons and no H is termed tertiary carbon. Thus, hydrogen linked to such carbon is referred as tertiary.

Answer 14

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Answer 16

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Answer 17

Ch. 3.1 - Prob. 3.2TIY Ch. 3.1 - Prob. 3.3E Ch. 3.4 - Prob. 3.5TIY Ch. 3.5 - Prob. 3.6E Ch. 3.7 - Prob. 3.7E Ch. 3.7 - Prob. 3.9TIY Ch. 3.9 - Prob. 3.11TIY Ch. 3.11 - Prob. 3.12E Ch. 3 - Prob. 15P Ch. 3 - Prob. 16P

Solution Summary: The author explains the number of constitutional isomeric monohalogenated products that can form from butane.

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