Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 21, Problem 21.71QP
Describe the removal of SO2 by CaO (to form CaSO3) in terms of a Lewis acid-base reaction.
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Write the reaction quotient, Qc, for each of the following reactions:(a) The first step in nitric acid production, NH3(g) + O2(g) ⇌ NO(g) + H2O(g)(b) The disproportionation of nitrogen monoxide, NO(g) ⇌ N2O(g) + NO2(g)
The reaction of calcium hydride, CaH2, with water can be characterized as a Lewis acid-base reaction:
Identify the Lewis acid and the Lewis base among the reactants. The reaction is also an oxidation-reduction reaction. Identify the oxidizing agent, the reducing agent, and the changes in oxidation number that occur in the reaction.
Explain, using Le Châtelier’s principle, why the equilibrium constant for the formation of NO from N2 and O2 increases with increasing temperature?
Chapter 21 Solutions
Chemistry: Atoms First
Ch. 21.2 - The bond enthalpy of O2 is 49S.7 kJ/mol. Calculate...Ch. 21.2 - Prob. 1PPACh. 21.2 - Prob. 1PPBCh. 21.2 - Prob. 1PPCCh. 21.2 - Prob. 21.2.1SRCh. 21.2 - Prob. 21.2.2SRCh. 21.5 - Prob. 21.2WECh. 21.5 - Prob. 2PPACh. 21.5 - Prob. 2PPBCh. 21.5 - Prob. 2PPC
Ch. 21.5 - Prob. 21.5.1SRCh. 21.5 - Prob. 21.5.2SRCh. 21.8 - Prob. 21.3WECh. 21.8 - Prob. 3PPACh. 21.8 - Prob. 3PPBCh. 21.8 - Prob. 3PPCCh. 21.8 - Prob. 21.8.1SRCh. 21 - Prob. 21.1QPCh. 21 - Prob. 21.2QPCh. 21 - Prob. 21.3QPCh. 21 - Prob. 21.4QPCh. 21 - Prob. 21.5QPCh. 21 - Prob. 21.6QPCh. 21 - Prob. 21.7QPCh. 21 - Prob. 21.8QPCh. 21 - Prob. 21.9QPCh. 21 - Prob. 21.10QPCh. 21 - Prob. 21.11QPCh. 21 - Prob. 21.12QPCh. 21 - Prob. 21.13QPCh. 21 - Prob. 21.14QPCh. 21 - Prob. 21.15QPCh. 21 - Prob. 21.16QPCh. 21 - Prob. 21.17QPCh. 21 - Prob. 21.18QPCh. 21 - Prob. 21.19QPCh. 21 - Prob. 21.20QPCh. 21 - Prob. 21.21QPCh. 21 - Prob. 21.22QPCh. 21 - Prob. 21.23QPCh. 21 - Prob. 21.24QPCh. 21 - Prob. 21.25QPCh. 21 - Prob. 21.26QPCh. 21 - Prob. 21.27QPCh. 21 - Prob. 21.28QPCh. 21 - Prob. 21.29QPCh. 21 - Prob. 21.30QPCh. 21 - Prob. 21.31QPCh. 21 - Prob. 21.32QPCh. 21 - Prob. 21.33QPCh. 21 - Prob. 21.34QPCh. 21 - Prob. 21.35QPCh. 21 - Prob. 21.36QPCh. 21 - Prob. 21.37QPCh. 21 - Prob. 21.38QPCh. 21 - Prob. 21.39QPCh. 21 - Calcium oxide or quicklime (CaO) is used in...Ch. 21 - Prob. 21.41QPCh. 21 - Prob. 21.42QPCh. 21 - Prob. 21.43QPCh. 21 - Prob. 21.44QPCh. 21 - Prob. 21.45QPCh. 21 - Prob. 21.46QPCh. 21 - Prob. 21.47QPCh. 21 - Prob. 21.48QPCh. 21 - Prob. 21.49QPCh. 21 - Prob. 21.50QPCh. 21 - In which region of the atmosphere is ozone...Ch. 21 - The gas-phase decomposition of peroxyacetyl...Ch. 21 - Prob. 21.53QPCh. 21 - Prob. 21.54QPCh. 21 - Prob. 21.55QPCh. 21 - Prob. 21.56QPCh. 21 - Prob. 21.57QPCh. 21 - Prob. 21.58QPCh. 21 - A concentration of 8.00 102 ppm by volume of CO...Ch. 21 - Prob. 21.60QPCh. 21 - Briefly describe the harmful effects of the...Ch. 21 - Prob. 21.62QPCh. 21 - Prob. 21.63QPCh. 21 - Prob. 21.64QPCh. 21 - Prob. 21.65QPCh. 21 - Prob. 21.66QPCh. 21 - Prob. 21.67QPCh. 21 - A glass of water initially at pH 7.0 is exposed to...Ch. 21 - Prob. 21.69QPCh. 21 - Prob. 21.70QPCh. 21 - Describe the removal of SO2 by CaO (to form CaSO3)...Ch. 21 - Which of the following settings is the most...Ch. 21 - Prob. 21.73QPCh. 21 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 21 - Prob. 21.75QPCh. 21 - Prob. 21.76QPCh. 21 - The carbon dioxide level in the atmosphere today...Ch. 21 - A 14-m by 10-m by 3.0-m basement had a high radon...Ch. 21 - Prob. 21.79QPCh. 21 - A person was found dead of carbon monoxide...Ch. 21 - Prob. 21.81QPCh. 21 - As stated in the chapter, carbon monoxide has a...Ch. 21 - Prob. 21.83QPCh. 21 - Prob. 21.84QPCh. 21 - Prob. 21.85QPCh. 21 - Prob. 21.86QP
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- How does CaO or CaCO2 remove SO2 from flue gases?arrow_forwardWrite the balanced chemical equation for conversion of Al(s) to KAl(SO4)2·12H2O(s) in aqueous solution.arrow_forwardExplain why the bond between B and Cl in the molecule BCl3 is shorter than would be expected for a single B—Cl bond.arrow_forward
- 1. Write the reaction quotient, Qc. for each of the following reactions: (a) The first step in nitric acid production, NH3(g) + O2(g) NO(g) + H₂O(g) (b) The disproportionation of nitrogen monoxide, NO(g) N₂O(g) + NO₂(g)arrow_forwardCompounds such as NaBH₄, Al(BH₄)₃, and LiAlH₄ arecomplex hydrides used as reducing agents in many syntheses.(a) Give the oxidation state of each element in these compounds.(b) Write a Lewis structure for the polyatomic anion in NaBH₄,and predict its shape.arrow_forwardAn impurity sometimes found in Ca₃(PO₄)₂ is Fe₂O₃, whichis removed during the production of phosphorus as ferrophos-phorus(Fe₂P). (a) Why is this impurity troubling from an eco-nomic standpoint? (b) If 50. metric tons of crude Ca₃(PO₄)₂ contains 2.0% Fe₂O₃ by mass and the overall yield of phospho-rus is 90.%, how many metric tons of P₄ can be isolated?arrow_forward
- Arrange the following hydrides in the order of increasing acidic strength and justify the order: PH3,AsH3, NH3 And BiH3.arrow_forwardWrite the chemical reaction involved in the preparation of sulphur sol.arrow_forwardConsider the series of reactions to synthesize the alum (KAl(SO4 )2 · xH2O(s)) from the introduction. Assuming an excess of the other reagents, from one mole of potassium hydroxide KOH, how many moles of alum will be produced?arrow_forward
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