Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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A chemistry graduate student is given 100. mL of a 0.30M diethylamine ((C,H,) NH) solution. Diethylamine is a weak base with K,= 1.3 × 10 °. what
mass of (C,H5) NH,Br should the student dissolve in the (C,H,), NH solution to turn it into a buffer with pH = 10.94?
2
You may assume that the volume of the solution doesn't change when the (C,H,) NH,Br is dissolved in it. Be sure your answer has a unit symbol, and round
2
it to 2 significant digits.
What will be the effect of adding 0.5 mL of .1M HCL to 100 mL of an acetate buffer in which [CH3COOH] = [CH3COO] = 0.5M?
a) The pH will decrease slightly
b) The pH will increase slightly
c) The pH will increase significantly
d) The pH will decrease significantly
Briefly explain how one can increase the solubility of Ca3(PO4)2, a relatively insoluble compound?
Chapter 15 Solutions
Chemistry: An Atoms-Focused Approach
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- -5 A chemistry graduate student is given 450. mL of a 0.80M ammonia (NH,) solution. Ammonia is a weak base with K=1.8 × 10 °. What mass of NH¸Br should the student dissolve in the NH, solution to turn it into a buffer with pH =9.30? You may assume that the volume of the solution doesn't change when the NH,Br is dissolved in it. Be sure your answer has a unit symbol, and round it to 2 significant digits.arrow_forwardQ4. Calculate the pH of 1.00 L of the buffer 0.98 M CH3COONa/0.98 M CH3COOH after the addition of the following species. Ka for CH;COOH =1.8 x 10 (SHOW YOUR WORK) (a) pH after addition of 0.050 mol NaOH (b) pH after the addition of 0.138 mol HCIarrow_forwardSuppose the molar solubility of MgCO3 in water is x M, while its molar solubility in a 0.5 M solution of MgCl, is y M. Which of the following is correct? Ox=y O x >y Oxarrow_forward-4 What A chemistry graduate student is given 100. mL of a 1.10 M trimethylamine ((CH,) N) solution. Trimethylamine is a weak base with K, = 7.4 x 10 mass of (CH, NHB1 should the student dissolve in the (CH, N solution to turn it into a buffer with pH = 10.56? You may assume that the volume of the solution doesn't change when the (CH, NHB is dissolved in it. Be sure your answer has a unit symbol, and round it to 2 significant digits.arrow_forwardWhat are the factors that affect buffer capacity? Explain in 2-3 sentences.arrow_forwardBefore (mol) Change (mol) After (mol) ap here or pull up for additional resources A student was titrating a solution of HC₂H₂O₂ with a Sr(OH)₂ solution. Determine the pH at a particular point in the titration. Do this by constructing a BCA table and determining the pH. The value of Ka for HC₂H₂O₂ is 1.5 x 10%. Complete Parts 1-2 before submitting your answer. NEXT 40.0 mL of a 0.200 M HC₂H₂O₂ solution was titrated with 100.0 mL of 0.100 M Sr(OH)2 (a strong base). Fill in the ICE table with the appropriate value for each involved species to determine the moles of reactant and product after the reaction of the acid and base. You can ignore the amount of water in the reaction. HC,H,Oz(aq) 1.00 x 10² 0 -1.00 x 10-² + Question 7 of 8 0.100 1.20 x 10² OH(aq) 0.200 -1.20 x 10" 2.00 x 10-³ 2.00 x 10-² 2 -2.00 x 10" -2.00 x 10-² H₂O(l) 8.00 x 10" RESET -8.00 x 10" C,H,Or(aq) Subarrow_forwardA chemistry graduate student is given 100. mL of a 1.80M trimethylamine ((CH N solution. Trimethylamine is a weak base with K,=7.4 x 10 *. What (CH3), NHC1 should the student dissolve in the (CH3),N solution to turn it into a buffer with pH =10.99? mass of You may assume that the volume of the solution doesn't change when the (CH, NHCI is dissolved in it. Be sure your answer has a unit symbol, and round it to 2 significant digits.arrow_forwardHow can we solve questions 3 and 4? Calculate the pH of a 0.350 M solution of potassium phenolate, KC6H5O. Ka for phenol (CH5OH) is 1.0 x 10-10. How do the concentration/volumes of the buffer affect the buffer capacity? E.g., 50.0 mL of 0.10 M acetic acid solution with 50.0 mL of 0.10 M sodium acetate solution vs. the buffer you made in the lab (25.0 mL of 0.10 M acetic acid solution with 25.0 mL of 0.10 M sodium acetate solution).arrow_forwardAnswer using this data for the remaining questions on this page: For 1.0L of an acetic acid solution: Ka = 1.8 x 10-5 and [HA] = 0.250M 2. Calculate the pH of the solution. 3. What is the pka? 4. Calculate the pH of the solution if you make it a buffer by adding enough solid sodium acetate to make the concentration of acetate ion equal to 0.35M. The volume of the solution does not change. 5. What is the new concentration of [HA] if 2.0mL of 5.00M of HCI is added to 1.000L of the solution above? 6. What is the new pH?arrow_forward4. What is the pH at each of the following points in the titration of 25.00 mL of 0.100 M CH,CH;COOH with 0.100 M NaOH? a) before the addition of any NaOH; b) after the addition of 10.00 mL of 0.100 M NaOH; c) after the addition of 12.50 mL of 0.100 M NaOH; d) after the addition of 25.00 mL of 0.100 M NaOH; e) after the addition of 26.00 mL of 0.100 M NaOH.arrow_forwardQ:3-3 Consider a 1.00 L buffer made by adding 0.140 mol cyanic acid HCNO, and 0.110 mol potassium cyanate ,KCNO, to sufficient water. Calculate the pH a buffer (a) Before any acid or base is added; (b) after the addition of 0.015 mol of HNO3; (c) After the addition of 0.015 mol of KOH. In parts (b) and (c) assume the volume does not change . pka(HCNO)=3.48; ka(HCNO)= 3.3 X 104.arrow_forwardAt pH 10.0, only 0.019 g of MgCl2 will dissolve per 1 L of solution. What is the Ksp of magnesium hydroxide, Mg(OH)2?arrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
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