Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
Book Icon
Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Blurred answer
Students have asked these similar questions
Choose the reagent(s) that would be most likely to complete this reaction. HILL Y.... A B C D E BH3-THF H2O2, NaOH tBuOK CHCI 3 CH2I2 Zn/Cu mCPBA 1. Hg(OAc)2, H₂O 2. NaBH4, NaOH
Specify both the alcohol starting material and the reagents you would use in each step in a synthesis of the compound shown. If the synthesis requires only two steps enter "none" for step 3. OH Alcohol Starting Materials 1. methanol 2. ethanol 3. 1-propanol 4. 2-propanol 5. cyclohexanol a. LiAlH4 f. PBr3 b. H₂SO4 c. HCI d. HBr e. SOC1₂ Reagents available g. CrO3, H₂SO4, H₂O h. NaH i. CH3 MgBr; then H3O+ j. CH3 CH₂ MgBr; then H3O+ k. CH3 CH₂ CH₂ MgBr; then H3O+ I. C6H5 MgBr (phenylmagnesium bromide); then H3O+ m. (CH3)2 CHMgBr: then H3O+ n. Dess-Martin periodinane (DMP) Write the number/letters of the alchol/reagents in the boxes below. Alcohol starting material 4 Reagent for step 1 n Reagent for step 2 j Reagent for step 3 c
1. What is the IUPAC name of the compound? ..O 2. Which alkyl bromide is the best choice to use as a reagent in a Williamson ether synthesis of 2-propoxybutane? A Br A B OCH3 Br B 3. What is the product of this alkoxymercuration-demercuration reaction? OCH₂ C H₂CO Br 1. Hg(OAc)2, CH3OH 2. NaBH4 C H₂CO D D

Chapter 14 Solutions

Organic Chemistry (9th Edition)

Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning