Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Textbook Question
Chapter 13.SE, Problem 64GP
Compound F, a hydrocarbon with M+=96 in its mass spectrum, undergoes reaction with HBr to yield compound G. Propose structures for F and G, whose 13C NMR spectral data are given below.
Compound F
Broadband-decoupled 13C NMR: 27.6, 29.3, 32.2, 132.4 δ DEPT-90: 132.4 δ
DEPT-135: positive peak at 132.4 δ; negative peaks at 27.6, 29.3, 32.2 δ
Compound G
Broadband-decoupled 13C NMR: 25.1, 27.7, 39.9, 56.0 δ DEPT-90: 56.0 δ
DEPT-135: positive peak at 56.0 δ; negative peaks at 25.1, 27.7, 39.9 δ
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Chapter 13 Solutions
Organic Chemistry
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