Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 12, Problem 30P
List the following compounds in order from most reactive to least reactive toward nucleophilic addition:
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Rank the following compounds in order of increasing reactivity towards nucleophilic attack.
Rank the reactivity of the compounds below toward nucleophilic acyl
substitution by writing the compounds' letters in the proper blanks in the box below.
`NH
CI
Br
CH3
CH3
A
В
C
E
rank compounds for acyl substitution reactivity
most
least
reactive
reactive
Rank the compounds in each group in order of increasing reactivity in nucleophilic acyl substitution.
C6H5CO2CH3, C6H5COCl, C6H5CONH2
Chapter 12 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 12.1 - Prob. 1PCh. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3PCh. 12.1 - Prob. 4PCh. 12.2 - Prob. 5PCh. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7PCh. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9PCh. 12.5 - Prob. 10P
Ch. 12.5 - Prob. 12PCh. 12.5 - Write the mechanism for the reaction of acetyl...Ch. 12.5 - Prob. 14PCh. 12.6 - Prob. 16PCh. 12.7 - Prob. 17PCh. 12.7 - Prob. 18PCh. 12.7 - Prob. 19PCh. 12.8 - Prob. 20PCh. 12.8 - Prob. 21PCh. 12.8 - Prob. 22PCh. 12.9 - Which of the following are a. hemiacetals? b....Ch. 12.9 - Prob. 24PCh. 12.9 - Prob. 25PCh. 12.10 - Prob. 26PCh. 12.11 - Prob. 27PCh. 12 - Draw the structure for each of the following: a....Ch. 12 - Prob. 29PCh. 12 - List the following compounds in order from most...Ch. 12 - Show the reagents required to form the primary...Ch. 12 - Fill in the boxes:Ch. 12 - Indicate how the following compounds could be...Ch. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - Prob. 38PCh. 12 - Prob. 39PCh. 12 - Show two ways the following compound could be...Ch. 12 - Prob. 41PCh. 12 - Prob. 42PCh. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Prob. 46PCh. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Prob. 50PCh. 12 - Prob. 51PCh. 12 - Indicate how the following compounds could be...Ch. 12 - Prob. 53P
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- Classify each of the following species as a nucleophile or an electrophile:arrow_forwardRank the following esters in order of decreasing reactivity in the first slow step of a nucleophilic acyl substitution reaction (formation of the tetrahedral intermediate):Rank the same esters in order of decreasing reactivity in the second slow step of a nucleophilic acyl substitution reaction (collapse of the tetrahedral intermediate).arrow_forwardArrange the following compounds in order of increasing reactivity in nucleophilic acyl substitution. Y OA> B>C OB> C > A OC> A > B O C> B> A OB> A >C OA> C > B Barrow_forward
- Rank the compounds in each group in order of increasing reactivity toward nucleophilic attack.arrow_forwardDenote how many nucleophilic centers are present in the following molecular structure (in case of polar bonds show clearly on the structure the dipoles õ+ and d-). :o: сноarrow_forwardRank the following esters from most reactive to least reactive in the first slow step of a nucleophilic acyl substitution reaction (formation of the tetrahedral intermediate): Rank the same esters from most reactive to least reactive in the second slow step of a nucleophilic acyl substitution reaction (collapse of the tetrahedral intermediate).arrow_forward
- Rank the following compounds in order of increasing reactivity in a substitution reaction with −CN as nucleophile.arrow_forwardRank group of compounds from most reactive to least reactive toward electrophilic aromatic substitution: toluene, p-cresol, benzene, p-xylenearrow_forward1. Rank the following substances in order of increasing reactivity towards nucleophilic acyl substitution (the least reactive is 1 and the most reactive is 5). 요 OPh HOarrow_forward
- Rank the following compounds from most reactive to least reactive toward nucleophilic addition:arrow_forwardRank the following compounds in order of increasing reactivity during an electrophilic substitution reactionarrow_forwardRank the following compounds in order of increasing reactivity in nucleophilic addition.arrow_forward
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