Modern Physics
3rd Edition
ISBN: 9781111794378
Author: Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher: Cengage Learning
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Chapter 11, Problem 9Q
To determine
The reason for noble gases being monoatomic rather than diatomic.
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Chapter 11 Solutions
Modern Physics
Ch. 11.2 - Compare the effective force constant for the CO...Ch. 11 - Prob. 1QCh. 11 - Prob. 2QCh. 11 - Prob. 3QCh. 11 - Prob. 4QCh. 11 - Prob. 5QCh. 11 - Prob. 7QCh. 11 - Prob. 8QCh. 11 - Prob. 9QCh. 11 - Prob. 1P
Ch. 11 - Use the data in Table 11.2 to calculate the...Ch. 11 - The CO molecule undergoes a rotational transition...Ch. 11 - Prob. 4PCh. 11 - Prob. 5PCh. 11 - Prob. 6PCh. 11 - Prob. 7PCh. 11 - The v = 0 to v = 1 vibrational transition of the...Ch. 11 - Consider the HCl molecule, which consists of a...Ch. 11 - Prob. 10PCh. 11 - Prob. 11PCh. 11 - Prob. 12PCh. 11 - Prob. 13PCh. 11 - Prob. 14PCh. 11 - Prob. 15PCh. 11 - Prob. 18P
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- Plot the Fermi-Dirac function f(E) versus the energy ratio E/EF at room temperature T=300oK.(Assume EF independent of temperature.)If EF=5ev, determine the energy values at which f (E)=0.5.0.7.0.9 and 0.95?arrow_forwarda) Starting from a general fornula of desity of States. g(k) dk= Vkdk 272 Show that g(w) dw= 3x Vw°dw for Phonons under the assumption thait the phonoh dre aicoustic, meaning U = does not depend 3. on W or k. 3N b) In a solid of N atoms, there are vibrational modes(phonons) with the highat frequercy Wp.arrow_forwardShow that the kinetic energy (U0) of a 3D gas of N free electrons at 0 K is U0=3/5NEF.arrow_forward
- Suppose we have an ideal fermion gas of identical particles in a "box" at T = 0 K. Which of the following statements are true? a. The multiplicity of the gas is =1 b. The multiplicity of the gas is =N! C. If the gas consists of electrons with densities that correspond to the typical densities of conduction electrons in metals, only a part of the electrons can contribute to the heat capacity of the system as the temperature rises. d. If the gas consists of electrons with densities corresponding the typical densities of conduction electrons in metals, all electrons can easily contribute to the heat capacity of the system as the temperature rises.arrow_forwardIn a diatomic gas why should it be more difficult to excite the vibrational mode than the rotational mode?arrow_forwardThe vibrational wavenumber of HBr is 264 cm-1 Evaluate the vibrational partition function of HBr at 298 K using both the exact and the approximate expressions.arrow_forward
- Estimate the contribution of the spin to the molar entropy of a solid sample of a d-metal complex with S = 5/2.arrow_forwardS² = 4f² cos² TC h+2k 3 + Prove that the composition factor of the Zn unit cell of the hexagonal compact structure HCP, which coordinates | The atoms in it are (1/3,2/3,1/2), (0,0,0) given by the relationshiparrow_forwardc) Let's think about this. To a first approximation, a diatomic molecule can be represented by a harmonic oscillator. However, we learned that the Morse oscillator provides a better representation of a diatomic molecule. The figure below shows the harmonic and Morse potential energy curves for a diatomic molecule, along with corresponding vibrational wavefunctions. How do you expect the average bond length of a diatomic molecule would change if the molecule transitions from the ground to any of the excited vibrational levels when: 1) the molecule is represented by the harmonic potential, and 2) the molecule is represented by the Morse potential? Explain your reasoning. Harmonic potential Morse potential Vs V4 Vs V1 Vo vo Reg Regarrow_forward
- The R-branch of a vibrational-rotational spectrum consists of lines of increasing frequency. O True False Question 9 3 When the total energy of a system is a sum of individual contributions, the partition function is a product of individual contributions. O True O Falsearrow_forwardp9C.1 Familiarity with the magnitudes of overlap integrals is useful when con- sidering bonding abilities of atoms, and hydrogenic orbitals give an indication of their values. (a) The overlap integral between two hydrogenic 2s orbitals is 1 ( ZR ZR +. 2а, " 12 а, 1 + ZR 240 a, -ZR/Z0 S(2s, 2s)={1+ Plot this expression. (b) For what internuclear distance is S(2s,2s) = 0.50? (c) The side-by-side overlap of two 2p orbitals of atoms of atomic number Z is ZR 1 ( ZR ZR S(2p,2p) ={1+ 10 a, 2a, 120 a. Plot this expression. (d) Evaluate S(2s,2p) at the internuclear distance you calculated in part (b).arrow_forwardThe equilibrium dissociation energy of O2 is De = 4.314 ev. The basic vibration frequency of O2 is f = 1620.0 cm -1. So how much energy is actually needed to dissociate O2 molecules at n = 3 vibrational level? Give your answer in EV.arrow_forward
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