Concept explainers
Which of the following will have the lowest total vapor pressure at 25°C?
a. pure water (vapor pressure = 23.8 torr at 25°C)
b. a solution of glucose in water with
c. a solution of sodium chloride in water with χNaCl = 0.01
d. a solution of methanol in water with
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Chapter 10 Solutions
Chemistry: An Atoms First Approach
- The freezing point of a 0.21 m aqueous solution of H2SO4 is -0.796C. (a) What is i? (b) Is the solution made up primarily of (i) H2SO4 molecules only? (ii) H+ and HSO4- ions? (iii) 2H+ and 1SO42- ions?arrow_forwardButane, C4H10, has been suggested as the refrigerant in household compressors such as those found in air conditioners. (a) To what extent is butane soluble in water? Calculate the butane concentration in water if the pressure of the gas is 0.21 atm. (kH = 0.0011 mol/kgbar at 25 C) (b) If the pressure of butane is increased to 1.0 atm, does the butane concentration increase or decrease?arrow_forwardThe freezing point of a 0.11 m solution of HNO2 is -0.20C. (a) What is i for the solution? (b) Is the solution made (i) of HNO2 molecules only? (ii) of H+ and NO2- only? (iii) of more HNO2 molecules than H+ ions? (iv) primarily of H+ and NO2- ions with some HNO2 molecules?arrow_forward
- Some lithium chloride, LiCl, is dissolved in 100 mL of water in one beaker, and some Li2SO4 is dissolved in 100 mL of water in another beaker. Both are at 10 C, and both are saturated solutions; some solid remains undissolved in each beaker. Describe what you would observe as the temperature is raised. The following data are available to you from a handbook of chemistry:arrow_forwardFor each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Ammonia gas in water with P = 1 atm and T = 50C Ammonia gas in water with P = 1 atm and T = 90C b. Carbon dioxide gas in water with P = 2 atm and T = 50C Carbon dioxide gas in water with P = 1 atm and T = 50C c. Table salt in water with P = 1 atm and T = 60C Table salt in water with P = 1 atm and T = 50C d. Table sugar in water with P = 2 atm and T = 40C Table sugar in water with P = 1 atm and T = 70Carrow_forwardRefer to Figure 13.10 ( Sec. 13-4b) to answer these questions. (a) Does a saturated solution occur when 65.0 g LiCl is present in 100 g H2O at 40 C? Explain your answer. (b) Consider a solution that contains 95.0 g LiCl in 100 g H2O at 40 C. Is the solution unsaturated, saturated, or supersaturated? Explain your answer. (c) Consider a solution that contains 50. g Li2SO4 in 200. g H2O at 50 C. Is this solution unsaturated, saturated, or supersaturated? Explain your answer. Figure 13.10 Solubility of ionic compounds versus temperature.arrow_forward
- For each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Oxygen gas in water with P = 1 atm and T = 10C Oxygen gas in water with P = 1 atm and T = 20C b. Nitrogen gas in water with P = 2 atm and T = 50C Nitrogen gas in water with P = 1 atm and T = 70C c. Table salt in water with P = 1 atm and T = 40C Table salt in water with P = 1 atm and T = 70C d. Table sugar in water with P = 3 atm and T = 30C Table sugar in water with P = 1 atm and T = 80Carrow_forwardThe dispersed phase of a certain colloidal dispersion consists of spheres of diameter 1.0 102 nm. (a) What are the volume (V=43r2) and surface area (A = r2) of each sphere? (b) How many spheres are required to give a total volume of 1.0 cm3? What is the total surface area of these spheres in square meters?arrow_forward
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