Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition? You may assume no mixing with any ligand orbitals. +- +++ eg t29 1

Chemistry by OpenStax (2015-05-04)
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Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
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Chapter19: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 43E: For complexes of the same metal ion with no change in oxidation number, the stability increases as...
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Which of the three selection rules (spin, orbital, Laporte) are broken by the following
transition? You may assume no mixing with any ligand orbitals.
+-
+++ t2g
ea
1
O a.
Spin rule is obeyed, but the orbital and Laporte rule are broken.
O b.
The spin rule, the orbital rule, and the laporte rule are all broken.
O c. This purely d-d transition is not forbidden by any rule, so none are broken.
O d. Only the orbital rule is broken.
Transcribed Image Text:Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition? You may assume no mixing with any ligand orbitals. +- +++ t2g ea 1 O a. Spin rule is obeyed, but the orbital and Laporte rule are broken. O b. The spin rule, the orbital rule, and the laporte rule are all broken. O c. This purely d-d transition is not forbidden by any rule, so none are broken. O d. Only the orbital rule is broken.
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