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- A solution is made by dissolving 34.0 g of NaCl in 100 g of H2O at 0C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentratedThe dispersed phase of a certain colloidal dispersion consists of spheres of diameter 1.0 102 nm. (a) What are the volume (V=43r2) and surface area (A = r2) of each sphere? (b) How many spheres are required to give a total volume of 1.0 cm3? What is the total surface area of these spheres in square meters?Analysis of a compound gave 39.50% C, 2.21% H, and 58.30% Cl. When 0.855 g of this solid was dissolved in 7.50 g of naphthalene, the solution had a freezing point of 78.0C. The pure solvent freezes at 80.0C; its molal freezing point constant is 6.8C/m. a What is the molecular formula of the compound? b What is its molecular weight to the nearest 0.1 g?
- A solution is made by dissolving 0.455 g of PbBr2 in 100 g of H2O at 50C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentratedYou dissolve 1.0 mol of urea (H2NCONH2) in 270 g of water. The mole fraction of urea is (a) 3710 3 (b) 0.063 (c) 16 (d) 1.0 and its molality is (a) 1.0 (b) 3.7 (c) 0.063 (d) 0.27A forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?
- Refer to Figure 13.10 ( Sec. 13-4b) to answer these questions. (a) Does a saturated solution occur when 65.0 g LiCl is present in 100 g H2O at 40 C? Explain your answer. (b) Consider a solution that contains 95.0 g LiCl in 100 g H2O at 40 C. Is the solution unsaturated, saturated, or supersaturated? Explain your answer. (c) Consider a solution that contains 50. g Li2SO4 in 200. g H2O at 50 C. Is this solution unsaturated, saturated, or supersaturated? Explain your answer. Figure 13.10 Solubility of ionic compounds versus temperature.Which solute has the greatest effect on the boiling pointof 1.00 kg of water: 50.0 g of strontium chloride (SrCl2) or 150.0 g of carbon tetrachloride (CCl4) ? Justify youranswer.The solubility of benzoic acid (HC7H5O2), is 0.34 g/100 mL in water at 25C and is 10.0 g/100 mL in benzene (C6H6) at 25C. Rationalize this solubility behavior. (Hint: Benzoic acid forms a dimer in benzene.) Would benzoic acid be more or less soluble in a 0.1-M NaOH solution than it is in water? Explain.
- The freezing-point depression of a 0.091-m solution of CsCl is 0.320C. The freezing-point depression of a 0.091-m solution of CaCl2 is 0.440C. In which solution does ion association appear to be greater? Explain.Specifications for lactated Ringers solution, which is used for intravenous (IV) injections, are as follows to reach 100. mL of solution: 285315 mg Na+ 14.117.3 mg K+ 4.9Q.O mg Ca2+ 368408 mg Cl 231261 mg lactate, C3H5O3 a. Specify the amount of NaCl, KCl, CaCl2 2H2O, and NaC3H5O3 needed to prepare 100. mL lactated Ringers solution. b. What is the range of the osmotic pressure of the solution at 37C, given the preceding specifications?An unknown compound contains only carbon, hydrogen, and oxygen. Combustion analysis of the compound gives mass percents of 31.57% C and 5.30% H. The molar mass is determined by measuring the freezing-point depression of an aqueous solution. A freezing point of 5.20C is recorded for a solution made by dissolving 10.56 g of the compound in 25.0 g water. Determine the empirical formula, molar mass, and molecular formula of the compound. Assume that the compound is a nonelectrolyte.