Predict the major product of each of the following reactions or series of reactions. In cases involving an ortho/para-directing substituent where two products would be obtained, draw the product resulting from para-substitution only..
Predict the major product of each of the following reactions or series of reactions. In cases involving an ortho/para-directing substituent where two products would be obtained, draw the product resulting from para-substitution only..
Basic Clinical Laboratory Techniques 6E
6th Edition
ISBN:9781133893943
Author:ESTRIDGE
Publisher:ESTRIDGE
Chapter1: The Clinical Laboratory
Section1.8: Laboratory Math And Reagent Preparation
Problem 14RQ
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Predict the major product of each of the following reactions or series of reactions. In cases involving an ortho/para-directing substituent where two products would be obtained, draw the product resulting from para-substitution only..
Transcribed Image Text:a)
ô
ō
of
d)
Br₂
FeBr3
1.HNO3, H₂SO4
2. Br₂, FeBr3
1. Fuming H₂SO4
2. Cl₂, AICI3
1.
CI, AICI3
2. Zn(Hg), HCI, A
e)
O₂N
f)
g)
O₂N.
Br
CI.
OMe
CBr3
Fuming H₂SO4
OH
1. Cl₂, AICI 3
2. Na₂Cr₂O7, H₂SO4
HNO3
H₂SO4
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Step 1: In the presence of FeBr3,
VIEWStep 2: The initial step of nitration
VIEWStep 3: Sulfonic acid (SO3H)
VIEWStep 4: The benzene ring is initially treated to an acyl group (COCl)
VIEWStep 5: The aromatic ring would probably
VIEWStep 6: The ring is chlorinated in the presence of AlCl
VIEWStep 7: Because of opposing direction effects,
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