5-Chloro-1,3-cyclopentadiene (below) undergoes SN1 solvolysis in the presence of silver ion ex chlorine is doubly allylic and allylic halides normally ionize readily (Section 15.15). -CI
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- Alkyl halides undergo elimination reactions to produce alkenes by the reacting with strong bases as shown in the following reaction (see image). In general, compounds where the halogen is axial (axial position) are much more reactive than those in which they are in the equatorial position. Taking the above into account: a. Which of the following compounds would give a faster elimination reaction: cis-1-bromo-2-tert-butylcyclohexane or trans-1-bromo-2-tert-butylcyclohexane? Draw the corresponding structures and clearly explain the choice.A benzene ring alters the reactivity of a neighboring group in the so-called “benzylic” position, similarly to how a double bond alters the reactivity of groups in the “allylic” position. Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates. a) Use resonance structures to show the delocalization of the positive charge, negative charge, and unpaired electron of the benzyl cation, anion, and radical.Draw structural formulas for the major organic product(s) of the reaction shown below. LOH + CH3CCI **** AICI 3 You do not have to consider stereochemistry. • If no reaction occurs, draw the organic starting material. • Remember to include all of the formal charges on the atoms of any nitro groups. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the Separate multiple products using the + sign from the drop-down menu. 4
- [References] Draw structural formulas for the major organic product of the reagents shown. OCH3 OCH 3 . HNO3 H₂SO4 • You do not have to consider stereochemistry. Apply formal charges to any nitro groups. • If there is more than one major product possible, draw all of them. ● Separate multiple products using the + sign from the drop-down menu.Hydrohalogenation of alkenes in the presence of peroxide adds a halide at the vinyl position. Which halide can be used in UV-catalyzed hydrohalogenation reaction in the presence of diethyl ether to obtain alkyl halide. Note: Distillation of the diethyl ether used in the reaction resulted in a violent explosion. * Molecular fluorine, only molecular bromine, only Molecular chlorine only molecular iodine, only Bromine and Molecular Chlorine, only nah[Review Topics] Draw structural formulas for the major organic product of the reagents shown. CH3 CH3 HNO3 H₂SO4 • You do not have to consider stereochemistry. Apply formal charges to any nitro groups. • If there is more than one major product possible, draw all of them. • Separate multiple products using the + sign from the drop-down menu. ChemDoodle Sn [F
- 44a) Draw the bond-line structure of 1,4-dimethyl-cyclohexa-1,3-diene here: STRUCTURE: b) Circle all the sp²-hybridized carbons in your drawing of the structure. c) In the spaces below, draw two potential products from a chlorination reaction (addition of Cl2) with your first structure Product 1: Product 2:The compound below is treated with chlorine in the presence of light. H₂C CH3 H3C CH₂CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms.Draw the structure of (Z)-2,3-dichloro-4-methyl-2-hexene. • Consider E/Z stereochemistry of alkenes. • You do not have to explicitly draw H atoms. opy aste ChemDoodle
- Please draw the chemical structures of the following compounds a. (3Z,5S)-non-3-en-1-in-5-ole b. (1R,3S)-1-chloro-3-ethylcyclohexane3. Choose the answer that satisfy each statement. a. Under thermal conditions, (2E,4Z)-hexadiene undergoes a ring closure to form b. Under photochemical conditions, (2E,4Z)-hexadiene undergoes a ring closure to form A) conrotatory, cis-3,4-dimethylcyclobutene B) conrotatory, trans-3,4-dimethylcyclobutene C) disrotatory, cis-3,4-dimethylcyclobutene D) disrotatory, trans-3,4-dimethylcyclobuteneOrganic Chemistry Loudon Roberts & Company Publishers presented by Macmillan Leaning Draw the structures of two stereoisomeric alkenes that would give 3-hexanol or hexan-3-ol as the only major product of hydroboration followed by treatment with alkaline H,o,. OH Draw the two alkenes. Erase More Draw Rings Select CH