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Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition? You may assume no mixing with any ligand orbitals. t₂ e ↑ O a. This purely d-d transition is not forbidden by any rule, so none are broken O b. Spin rule is obeyed, but the orbital and Laporte rule are broken O c. The spin rule, the orbital rule, and the laporte rule are all broken O d. Only the orbital rule is broken

Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition? You may assume no mixing with any ligand orbitals. t₂ e ↑ O a. This purely d-d transition is not forbidden by any rule, so none are broken O b. Spin rule is obeyed, but the orbital and Laporte rule are broken O c. The spin rule, the orbital rule, and the laporte rule are all broken O d. Only the orbital rule is broken

Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section: Chapter Questions
Problem 72GQ: The square-planar complex Pt(en)Cl2 has chloride ligands in a cis configuration. No trans isomer is...
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Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition? You may assume no mixing with any ligand orbitals. t₂ ++ e O a. O b. O c. O d. Only the orbital rule is broken This purely d-d transition is not forbidden by any rule, so none are broken Spin rule is obeyed, but the orbital and Laporte rule are broken The spin rule, the orbital rule, and the laporte rule are all broken C
Transcribed Image Text:Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition? You may assume no mixing with any ligand orbitals. t₂ ++ e O a. O b. O c. O d. Only the orbital rule is broken This purely d-d transition is not forbidden by any rule, so none are broken Spin rule is obeyed, but the orbital and Laporte rule are broken The spin rule, the orbital rule, and the laporte rule are all broken C
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