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- 5-54 Ribose, an essential part of ribonucleic acid (RNA), has the following structure: H H H OH CHO Ribose Но но н но н (a) How many chirality centers does ribose have? Identify them. (b) How many stereoisomers of ribose are there? (c) Draw the structure of the enantiomer of ribose. (d) Draw the structure of a diastereomer of ribose.7-46 Assign E or Z configuration to each of the following compounds: (a) НОСH2 CH3 (b) HO2C H C=C H3C H. OCH3 (c) NC CH3 (d) CH3O2C CH=CH2 C=C C=C CH3CH2 CH2OH HO2C CH,CH35-39 ieal connaation of themanuomer of (2S,4R)- 2,4-0ctanedioHA diol is a compoud with two -OH groups.) 5-40 What are the stereochemical configurations of the two diastereomers of (2S,4R)-2,4-0ctanediol? (A diol is a compound with two -OH groups.) 5-41 Orient each of the fl the lowest-ranked group
- Problem 7. How will you distinguish the two members of each of the following pairs of compound by their IR spectra: (a) CH;CH2C=CH and CH3CH, C=N (b) RNH2 and RCONH, (с) CH,СОСH; аand CH;CH—CHCH-ОН (d) CН-—CH—0-СH; and CH CH-CНО (e) CH;CH2CHO and CH;COCH3Consider the given compound below: Among the following compounds provided, the compound highlighted in blue. Compound III Compound I Identical Compound II Enantiomer ◆ NH₂ -F Diastereomer ◆ HS HS OHC OH HO Br Br HOCHO - F -SH NH₂ whether they are identical, enantiomer, or diastereomer with respect to NH₂ -F # Br || CHO NH₂ F+SH HO Br CHO5 How many asymmetric carbons in this compound H H H Br H H H H-C-C-C -C-Ć-C-Ċ -H H Č H H H CI H O3 O t mN
- 5-34 Eight alcohols have the formula C5H120. Draw them. Which are chiral? 5-35 Draw compounds that fit the following descriptions: (a) A chiral alcohol with four carbons (b) A chiral carboxylic acid with the formula C5H1002 (c) A compound with two chirality centers (d) A chiral aldehyde with the formula C3H5BrO11) Label each carbon center as a "R" or "S" center in the following molecules H Br Br X L CBr3 Ph CN 12) What is the correct name for the following molecule? Br H (A) (4S, 2S)-4-bromo-3,3-dimethyl-2-pentanol (B) (4S, 2R)-4-bromo-3,3-dimethyl-2-pentanol (C) (4R, 2S)-4-bromo-3,3-dimethyl-2-pentanol (D) (4R, 2R)-4-bromo-3,3-dimethyl-2-pentanol (E) (4R, 2R)-2-bromo-3,3-dimethyl-4-pentanol 11. HO!!!!!! |||||ONWhat is the configuration, Z or E, of each of the following double bonds? (a) Br (b) Н Br (c) H H2C-CH3 (d) F 15NH2 С— C= H3C CI CI H3C CI CI H14N-CH3
- Which set is considered as stereo isomers among below: Br xx u u xohr Br Br H₂C g) h) i) 8- & Br CH₂ D H₂C 0:08 Br H₂C CH3CH2CH2CH2CH3 CH3CH(CH3)OCH2CH3 2-Methylbutane 2-Methylpropane CH₂ H₂C, Br & H CH₂ 3-Methylpentane (15 iso-Butane CH₂ -0:11Choose the terms that best describe the transformation shown below: •R:D Br Br both regioselective and stereospecific O regioselective neither regioselective nor stereospecific O stereospecificWhich choice correctly represents the structure below as a wedge-dash structure with any/all stereocenters correctly labeled with their absolute configuration? CH₂ H CI H OI O II O III O IV OV 110 2 IV 11 |||