Using the table of the weak base below, you have chosen Methylamine as your weak base in the buffer solution. You have already added enough of the conjugate acid salt to make the buffer solution concentration at 0.48 M in this salt. The desired pH of the buffer should be equal to 9.75. Values of K, for Some Common Weak Bases Conjugate Acid Name Formula 1.8 × 10-5 4.38 × 10-4 5.6 × 10–4 3.8 × 10-10 1.7 x 10-9 NH4 CH;NH3* NH3 CH;NH2 C¿H;NH2 CH;NH2 C;H;N Ammonia Methylamine Ethylamine Aniline C¿H§NH3* CH;NH;* C;H;NH+ Pyridine 3. Compute the concentration of the weak base in Molarity. (round off final answer to 4 decimal places)

Using the table of the weak base below, you have chosen Methylamine as your weak base in the buffer solution. You have already added enough of the conjugate acid salt to make the buffer solution concentration at 0.48 M in this salt. The desired pH of the buffer should be equal to 9.75. Values of K, for Some Common Weak Bases Conjugate Acid Name Formula 1.8 × 10-5 4.38 × 10-4 5.6 × 10–4 3.8 × 10-10 1.7 x 10-9 NH4 CH;NH3* NH3 CH;NH2 C¿H;NH2 CH;NH2 C;H;N Ammonia Methylamine Ethylamine Aniline C¿H§NH3* CH;NH;* C;H;NH+ Pyridine 3. Compute the concentration of the weak base in Molarity. (round off final answer to 4 decimal places)

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter15: Acid-base Equilibria

Section: Chapter Questions

Problem 8ALQ: You have a solution of the weak acid HA and add some of the salt NaA to it. What are the major...

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Using the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.
What is the pH of a buffer that is 0.150 M in a weak acid and 0.150 M in the acids conjugate base? The acids ionization constant is 6.8 106.
Sulfanilic acid (NH2C6H4SO3H) is used in manufacturing dyes. It ionizes in water according to the equilibrium equation NH2C6H4SO3H(aq)+H2O(l)NH2C6H4SO3(aq)+H3O+(aq)Ka=5.9104 A buffer is prepared by dissolving 0.20 mol of sulfanilicacid and 0.13 mol of sodium sulfanilate (NaNH2C6H4SO3) in water and diluting to 1.00 L. Compute the pH of the solution. Suppose 0.040 mol of HCl is added to the buffer.Calculate the pH of the solution that results.
Write the chemical equation and the expression for the equilibrium constant, and calculate Kb for the reaction of each of the following ions as a base. (a) sulfate ion (b) citrate ion
A solution of weak base is titrated to the equivalence point with a strong acid. Which one of the following statements is most likely to be correct? a The pH of the solution at the equivalence point is 7.0. b The pH of the solution is greater than 13.0. c The pH of the solution is less than 2.0. d The pH of the solution is between 2.0 and 7.0. e The pH of the solution is between 7.0 and 13.0. The reason that best supports my choosing the answer above is a Whenever a solution is titrated with a strong acid, the solution will be very acidic. b Because the solution contains a weak base and the acid (titrant) is used up at the equivalence point, the solution will be basic. c Because the solution contains the conjugate acid of the weak base at the equivalence point, the solution will be acidic.
Calculate the pH of solutions that are 0.25 M formic acid and 0.40 M sodium formate. 0.50 M benzoic acid and 0.15 M sodium benzoate.
Methyl orange, HMO, is a common acid-base indicator. In solution it ionizes according to the equation: HMOaqH+aq+MO-aqredyellow If methyl orange is added to distilled water, the solution turns yellow. If 1 drop or two of 6 M HCl is added to the yellow solution, it turns red. If to that solution one adds a few drops of 6 M NaOH, the color reverts to yellow. a. Why does adding 6 M HCl to the yellow solution of methyl orange tend to cause the color to change to red? Note that in solution HCl exists as H+ and Cl- ions. b. Why does adding 6 M NaOH to the red solution tend to make it turn back to yellow? Note that in solution NaOH exists as Na+ and OH- ions. How does increasing OH- shift Reaction 3 in the discussion section? How would the resulting change in H+ affect the dissociation reaction of HMO?
8-71 Explain why you do not need to know the chemical formula of a buffer compound to use it.
You have a solution of the weak acid HA and add some of the salt NaA to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
Which of these combinations is the best to buffer the pH at approximately 9? Explain your choice. CH3COOH/NaCH3COO HCl/NaCl NH3/NH4Cl
A quantity of 0.25 M sodium hydroxide is added to a solution containing 0.15 mol of acetic acid. The final volume of the solution is 375 mL and the pH of this solution is 4.45. a What is the molar concentration of the sodium acetate? b How many milliliters of sodium hydroxide were added to the original solution? c What was the original concentration of the acetic acid?

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