Use acid-base titration to determine the concentration of: – A weak acid: CH3COOH 0.100 M NaOH (standardized) •0.100 M HCl 0.100 M CH3COOH Phenolphthalein is used for endpoint determination – Changes from colourless to pink as a solution becomes more basic • Only need 2-3 drops per titration • pH range: 8.3-10

Fundamentals Of Analytical Chemistry
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Author:Skoog
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Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.18QAP
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Use acid-base titration to determine the
concentration of:
– A weak acid: CH3COOH

0.100 M NaOH (standardized)
•0.100 M HCl
0.100 M CH3COOH

Phenolphthalein is used for endpoint determination
– Changes from colourless to pink as a solution becomes more basic
• Only need 2-3 drops per titration
• pH range: 8.3-10

Data
• Determine the equivalence point of each acid by using:
- pH meter:
• HCI – pH=7.00
• CH,COOH
- Indicator: the point at which the indicator turns "pink"
Calculation of the acid concentration:
- [acid]=(VNAOH at equivalence mL · 0.100 M)/10 mL
Compare to the accepted concentration of the acids:
- HCI: 0.100 M
- сн,сOон: 0.100 М
Use acid-base titration to determine the
concentration of:
- A strong acid: HCI
0.100 M NAOH (standardized)
•0.100 M HCI
0.100 M Cнзсоон
Phenolphthalein is used for endpoint determination
- Changes from colourless to pink as a solution becomes more basic
• Only need 2-3 drops per titration
• pH range: 8.3-10
Procedure - Titration of Acid
• Ensure that the initial reading of the burette is recorded and that the pH meter is fully
submerged into the acid solution before continuing.
• Add NaOH from the burette to the acid solution in portions (total volume added: 2, 4,
6, 7, 7.5, 8, 8.5, 9, 9.2, 9.4, 9.6, 9.8, 10.0, 10.2, 10.4, 10.6, 10.8, 11, 12, 14, 16, 18,
20 mL) making sure to write the exact volume added each time and the
corresponding pH when it has stabilized.
• Record the initial and final burette volume, the pH, and indicator colour in a table
(see below for an example).
Initial
Final
Volume
pH
Colour of
volume (* volume
(+ 0.05
mL)
added
indicator
0.05 mL)
(+ ? mL)
2.10
4.20
2.10
Transcribed Image Text:Data • Determine the equivalence point of each acid by using: - pH meter: • HCI – pH=7.00 • CH,COOH - Indicator: the point at which the indicator turns "pink" Calculation of the acid concentration: - [acid]=(VNAOH at equivalence mL · 0.100 M)/10 mL Compare to the accepted concentration of the acids: - HCI: 0.100 M - сн,сOон: 0.100 М Use acid-base titration to determine the concentration of: - A strong acid: HCI 0.100 M NAOH (standardized) •0.100 M HCI 0.100 M Cнзсоон Phenolphthalein is used for endpoint determination - Changes from colourless to pink as a solution becomes more basic • Only need 2-3 drops per titration • pH range: 8.3-10 Procedure - Titration of Acid • Ensure that the initial reading of the burette is recorded and that the pH meter is fully submerged into the acid solution before continuing. • Add NaOH from the burette to the acid solution in portions (total volume added: 2, 4, 6, 7, 7.5, 8, 8.5, 9, 9.2, 9.4, 9.6, 9.8, 10.0, 10.2, 10.4, 10.6, 10.8, 11, 12, 14, 16, 18, 20 mL) making sure to write the exact volume added each time and the corresponding pH when it has stabilized. • Record the initial and final burette volume, the pH, and indicator colour in a table (see below for an example). Initial Final Volume pH Colour of volume (* volume (+ 0.05 mL) added indicator 0.05 mL) (+ ? mL) 2.10 4.20 2.10
Apparatus - Burette
24
10
25
Reading
9.63 ml
Reading
24.16 ml
Titration I
Titration 2
Final Reading (ml)
9.63 + 0.05 24.16 ± 0.05
www.indigo.com
Initial Reading (ml)
0.00 + 0.05
0.00 + 0.05
Total Volume (ml)
9.63 + 0.10 24.16 ± 0.10
Acid-Base Titration
Strong Acid-Strong Base
PH
Initial Burette Reading
Final Burette Reading
Total Volume added
(mL)
(mL)
0.00
(mL)
0.00
1.89
0.00
1.97
0.00
2.02
2.02
2.09
2.25
4.02
4.02
2.02
4.02
6.02
6.02
2.49
6.02
8.01
8.01
2.97
8.01
9.81
9.81
3.07
9.81
10.02
10.02
3.20
3.65
10.02
10.21
10.21
10.21
10.46
10.46
4.39
10.46
10.76
10.76
6.05
10.76
10.96
10.96
10.72
11.61
11.89
12.01
10.96
11.96
13.86
11.96
11.96
13.86
13.86
15.96
15.96
15.96
17.86
17.86
20.02
17.86
12.12
20.02
-- ---
Transcribed Image Text:Apparatus - Burette 24 10 25 Reading 9.63 ml Reading 24.16 ml Titration I Titration 2 Final Reading (ml) 9.63 + 0.05 24.16 ± 0.05 www.indigo.com Initial Reading (ml) 0.00 + 0.05 0.00 + 0.05 Total Volume (ml) 9.63 + 0.10 24.16 ± 0.10 Acid-Base Titration Strong Acid-Strong Base PH Initial Burette Reading Final Burette Reading Total Volume added (mL) (mL) 0.00 (mL) 0.00 1.89 0.00 1.97 0.00 2.02 2.02 2.09 2.25 4.02 4.02 2.02 4.02 6.02 6.02 2.49 6.02 8.01 8.01 2.97 8.01 9.81 9.81 3.07 9.81 10.02 10.02 3.20 3.65 10.02 10.21 10.21 10.21 10.46 10.46 4.39 10.46 10.76 10.76 6.05 10.76 10.96 10.96 10.72 11.61 11.89 12.01 10.96 11.96 13.86 11.96 11.96 13.86 13.86 15.96 15.96 15.96 17.86 17.86 20.02 17.86 12.12 20.02 -- ---
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