The picture below represents a molecular orbital from 1, 3-butadiene. How many nodesdoes this orbital have? Is this a bonding or anti-bonding molecular orbital?d.1 nodes, anti-bonding2 nodes, anti-bondinga. O nodes, bondingb. 1 node, bondingC.نن

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Answered: The picture below represents a…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter10: Molecular Structure And Bonding Theories

Section: Chapter Questions

Problem 10.93QE

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сс с C-C= C C-C C- C C a. Complete the formula, number the carbon atoms and name the molecule b. Draw and label in terms of the overlapping hybrid orbitals forming each bond c. Identify the hybrid orbitals forming each bond For your answers for letters d,e,f, give the number of the C atom (from a) only (ex. C10 - C11) d. Which C to C bond is the strongest e. Which C to H bond is the most polar f. Which C to C bond is the least free to rotate g. What is the mobile bond order
b. Explain in molecular orbital terms the changes in H-H inter-nuclear distance that occurs as the molecular H2 is ionized first to H2* and then to H,²*. Explain why the bond order of N2 is greater than that of N2*, but the bond order of O2 is less than that of O2*.
17. Which of the following does have delocalized molecular orbitals? Z of N = 7, O = 8, H = 1, C = 6 Hint: in the followings the overall charge is shown in the parenthesis. a.C03(-2)b.CH4c.NH3d.H20
MISSED THIS? Read Section 11.7 (Pages 457-470); Watch KCV 11.7. IWE 11.8. Write a hybridization and bonding scheme for each molecule. tab hift esc caps lock fn . ^ control FOOD BES ! 1 19 FI A 1 option 2 Z W S # 3 X H command 80 F3 E D $ 4 C In the sketch of the structure of SO₂ label all bonds. Drag the appropriate labels to their respective targets. Labels can be used once, more than once, or not at all. a FA R o: S(p)-0(p) o: S(p)-0(sp) F Lone pair in ap orbital : S(sp)-0(p) Lone pair in p orbital *: S(p)-0(p) : S(p)-0(sp) o: S(p)-0(p) Submit % 5 V Request Answer e T G 6 MacBook Air B Y H & 7 & 4 U N 8 J 4 bil I M ( 9 K DD O 8 1 H ) O L command P > - : I ; option { r ? 1 + = 11 I 40 F12 } Reset ] Help delete retur
MISSED THIS? Read Section 11.7 (Pages 457-470); Watch KCV 11.7, IWE 11.8. Write a hybridization and bonding scheme for each molecule. tab os lock esc . control D ES ! 1 FI Q A I option Z @ 2 p W S # 3 X H command 80 BU F3 E D $ 4 C a Part B In the sketch of the structure of CH₂Br₂ label all bonds. Drag the appropriate labels to their respective targets. Labels can be used once, more than once, or not at all. R F : C(sp) - H(p) o: C(ap)-H(p) T: C(sp) - Br(p) : C(p) - Br(p) :C(sp) - Br(p) o: C(sp)-Br(s) o: C(sp³) -H(s) : C(p)-H(p) Submit % 5 V FS Request Answer T G 6 MacBook Air B S F6 Y & 7 H F7 U N * 8 J D-II FB I M ( 9 K F9 H O . - - : d F11 { t command option [ + = ? I 11 I Reset 44 } 1 Help delete 0 retu
. ft MISSED THIS? Read Section 11.7 (Pages 457-470); Watch KCV 11.7. IWE 11.8. Write a hybridization and bonding scheme for each molecule. fn tab caps lock esc ^ control ! 1 OODY BES 10 F1 Q A Z 1 2 FZ W S # 3 X option command 80 F3 E D $ 4 C q F4 In the sketch of the structure of NF3 label all bonds. Drag the appropriate labels to their respective targets. Labels can be used once, more than once, or not at all. R T: N(p) - F(p) F Lone pair in p orbital Lone pair in s orbital o: N(p)-F(sp) Lone pair in ap orbital *: N(sp³) - F(p) e: N(sp¹)-F(p) o: N(p)-F(p) Submit % 5 V Request Answer ↓ FS T G 6 MacBook Air B Y H & 7 - I : ; option F11 { Review I Constants I Periodic Tab [ ? + 1 = 11 F12 Reset Help delete JU ] re 8
Give the ground state electron configuration for these molecules and deduce its bond order. a. H2+ b. O2- c. N2
1. Determine the bond order & magnetic behavior of the molecules: а. В* bond order: Atomic orbitals Molecular Atomic orbitals Atomic Molecular Atomic orbitals orbitals orbitals orbitals magnetic: b. Ne22+ bond order: 2p 2p 2p 2p magnetic: с. С2 Energy bond order: magnetic: d. F22- 2s 2s 2s 2s bond order: B2, C2, N2 02, F2, Ne, magnetic: 2011 Pearson Education, In е. Оz* bond order: magnetic:
a. Draw a molecular orbital diagram for the valence electrons in the helium-hydrogen diatomic (HeH). b. Label the 2 molecular orbitals as either bonding or antibonding and describe the key differences between these types of molecular orbitals in terms of electron density. c. Calculate the bond order of HeH based on your molecular orbital diagram. d. Do you expect the bond length in the cation HeH+ to be longer or shorter than in a neutral HeH? Justify your answer based on the molecular orbital diagram and bond order for both species.
3. Label the hybridization of any lone pair below that is an p orbital and provide a rationale for its hybridization. a. Abacavir - nucleoside reverse transcriptase inhibitor (anti-viral) used for the treatment of HIV/AIDS. НО. N OH O HN b. Doxycycline - A broad spectrum antibiotic with more than 8 million prescriptions given in the US every year. OH O OH|| 'N CH3 OH N NH₂ OH H3C CH3 NH₂
OC.. :0: H-Ć- O D.. H :0: H-C-C- -H- :0:
Draw and label in terms of the overlapping hybrid orbitals forming a. each bond b. Identify the molecular bond :O: H 1. СНз—С Н-С. C= N:

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The picture below represents a molecular orbital from 1, 3-butadiene. How many nodes does this orbital have? Is this a bonding or anti-bonding molecular orbital? d. 1 nodes, anti-bonding 2 nodes, anti-bonding a. O nodes, bonding b. 1 node, bonding C. نن