The Mohr indicator is chosen for an arbitrary titration. Which of the following statements would be INCORRECT regardingthe solutions to be titrated?A. The titrated solution would be buffered to a pH of 8 by adding acid/base prior to the addition of AgNO3 from the burette.B. A 20 mL sample of 0.1 M KI is titrated against 0.2 M AGNO3.C. Na2CrO4 Was added to the conical flask at the start of the titration.D. The analyte solution likely contains KBr.

Here we have to find a incorrect statement regarding the solution to be titrated-

Answered: The Mohr indicator is chosen for an…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter15: Additional Aqueous Equilibria

Section: Chapter Questions

Problem 93QRT: When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence...

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A 0.4000 M solution of nitric acid is used to titrate 50.00 mL of 0.237 M barium hydroxide. (Assume that volumes are additive.) (a) Write a balanced net ionic equation for the reaction that takes place during titration. (b) What are the species present at the equivalence point? (c) What volume of nitric acid is required to reach the equivalence point? (d) What is the pH of the solution before any HNO3 is added? (e) What is the pH of the solution halfway to the equivalence point? (f) What is the pH of the solution at the equivalence point?
A buffer solution is composed of 1.360 g of KH2PO4 and 5.677 g of Na2HPO4. (a) What is the pH of the buffer solution? (b) What mass of KH2PO4 must be added to decrease the buffer solution pH by 0.50 unit from the value calculated in part (a)?
Potassium hydrogen phthalate, known as KHP (molar mass = 204.22 g/mol), can be obtained in high purity and is used to determine the concentration of solutions of strong bases by the reaction HP(aq)+OH(aq)H2O(l)+P2(aq) If a typical titration experiment begins with approximately 0.5 g KHP and has a final volume of about 100 mL, what is an appropriate indicator to use? The pKa for HP is 5.51.
Consider the nanoscale-level representations for Question 110 of the titration of the aqueous weak acid HX with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: After a very small volume of titrant has been added to the initial HX solution? When enough titrant has been added to take the solution just past the equivalence point? Halfway to the equivalence point? At the equivalence point? Nanoscale representations for Question 110.
The weak base ethanolamine. HOCH2CH2NH2, can be titrated with HCl. HOCH2CH2NH2(aq)+H3O+(aq)HOCH2CH2NH3+(aq)+H2O(l) Assume you have 25.0 mL of a 0.010 M solution of ethanolamine and titrate it with 0.0095 M HCl. (Kb for ethanolamine is 3.2 107.) (a) What is the pH of the ethanolamine solution before the titration begins? (b) What is the pH at the equivalence point? (c) What is the pH at the halfway point of the titration? (d) Which indicator in Figure 17.11 would be the best choice to detect the equivalence point? (e) Calculate the pH of the solution after adding 5.00, 10.0, 20.0, and 30.0 mL of the acid. (f) Combine the information in parts (a), (b), (c), and (e), and plot an approximate titration curve.
A buffer solution with it pH of 12.00 consists of Na3PO4 and Na2HPO4. The volume of solution is 200.0 mL. (a) Which component of the buffer is present in a larger amount? (b) If the concentration of Na3PO4 is 0.400 M, what mass of Na2HPO4 is present? (c) Which component of the buffer must be added to change the pH to 12.25? What mass of that component is required?
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
Using Figure 17.11, suggest an indicator to use in each of the following titrations: (a) The weak base pyridine is titrated with HCl. (b) Formic acid is titrated with NaOH. (c) Ethylenediamine, a weak diprotic base, is titrated with HCl. Figure 17.11 Common acid-base indicators. The color changes occur over a range of pH values. Notice that o few indicators hove color changes over two different pH ranges.
A 0.2481 M solution of KOH is used to titrate 30.00 mL of 0.269 M hydrobromic acid. Assume that volumes are additive. (a) Write a balanced net ionic equation for the reaction that takes place during the titration. (b) What are the species present at the equivalence point? (c) What volume of KOH is required to reach the equivalence point? (d) What is the pH of the solution 1. before any KOH is added? 2. halfway to the equivalence point? 3. at the equivalence point?

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