the laboratory, POCl3 (phosphorus oxychloride) is used in the manufacture of phosphate esters, which are used in flame retardants and pesticides. It can be prepared by the following reaction at 25°C: 2 PCl3 (g) + O2 (g) --> 2 POCl3 (g) DH° = - 572 kJ; DG° = - 518.7 kJ Calculate DS°. Is the sign reasonable? Calculate S° for POCl3. Calculate DHf° for POCl3
the laboratory, POCl3 (phosphorus oxychloride) is used in the manufacture of phosphate esters, which are used in flame retardants and pesticides. It can be prepared by the following reaction at 25°C: 2 PCl3 (g) + O2 (g) --> 2 POCl3 (g) DH° = - 572 kJ; DG° = - 518.7 kJ Calculate DS°. Is the sign reasonable? Calculate S° for POCl3. Calculate DHf° for POCl3
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter9: Energy And Chemistry
Section: Chapter Questions
Problem 9.101PAE
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In the laboratory, POCl3 (phosphorus oxychloride) is used in the manufacture of phosphate esters, which are used in flame retardants and pesticides. It can be prepared by the following reaction at 25°C:
2 PCl3 (g) + O2 (g) --> 2 POCl3 (g)
DH° = - 572 kJ; DG° = - 518.7 kJ
- Calculate DS°. Is the sign reasonable?
Calculate S° for POCl3.
Calculate DHf° for POCl3.
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