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The IR frequency of C≡N¯ in fac-[IrCl3(C≡N)3] is 2200 cm-1. Estimate the IR frequency of C≡N¯ for fac-[IrF3(C≡N)3] with an explanation.
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- Unfortunately, carbon monoxide was not a common molecule when hemoglobin evolved, and the binding site does not distinguish between Oz and Co. When carbon monoxide is present, it can bind to some of the available hemoglobin sites, which prevents the hemoglobin from carrying oxygen. Fo* Fe* Fe* B. CO binds at an absorption site with energy €co = -3.45 × 10-20 J. Suppose there is a 1 to 100 ratio of CO to O2 present in the blood. For simplicity's sake, assume there are now 100 Oz molecules available to bind. 1. What are the possible states now, and what are their multiplicities?C8H8O produces an IR spectrum with 3063, 1686, 1646 cm signals. HNMR is a singlet at 2.6ppm (3H), and multiplet at 7.5 (5H). What is the productWhich of the following is true about fluorescence intensity of the molecule? I Fluorescence is observed in planar molecules and its intensity increase with an increase in the number of aromatic rings II When zinc is added to a hydroxyl quinoline solution the fluorescence intensity increased due to the formation of a complex which increases the rigidity of the molecule. III On increasing the intensity of the incident radiation the fluorescence intensity increases IV On increasing the concentration of the fluorigenic molecule, the fluorescence intensity increases. A plot of intensity vs concentration exhibita linear relation indefinitely in all concentration ranges. O a. II,III,IV O b. 1,11,1II,IV O. I,II,III O d. II,I,IV O e. I,II,IV
- What wavelength is the peak absorbance of CoCl2?1. The IR frequency of C≡N¯ in fac-[IrCl3(C≡N)3] is 2200 cm-1. Estimate the IRfrequency of C≡N¯ for fac-[IrF3(C≡N)3] with an explanation.2. State TWO (2) organometallic reactions that involve the concept of d ―p bonding.Absorbance at 453 nm 8393939 7 fl. oz./20 ml Beer-Lambert's Law (Spectrophotometry) #1 Fe (aq) + KSCN(s) FESCN "(aq) + K" (aq) 3+ To determine the moles of Fe (aq) in a 100. mL sample of an unknown solution, excess KSCN(s) is added to convert all the Fe (aq) into the dark red species FeSCN"(aq), as represented by the equation above. The absorbance of FESCN"(aq) at different concentrations is shown in the graph below. 2+ 0.50 目0.40 0.30 0.20 01 0. 0. 5 x 10-5 10 x 10-5 Concentration of FESCN2+ (M) If the absorbance of the mixture is 0.20 at 453 nm, haw many moles of Fe (aq) were present in the 100. mL sample? (Assume that any volume change due to adding the KSCN(s) Iis negligible.) 3+, 4x10-4 mol 3 x 104 mol (B) 4x 10-6 mol 3x 10-6 mol
- 3. Compound Z absorbs light of wavelength 320 nm. A 1.0 × 10–3 mol dm–3 solution of a compound Z gives an absorbance reading of 0.15 when placed in a solution cell of path length 1 cm. What is the value of the molar extinction (absorption) coefficient of Z? 4. A 0.100 mol dm−3 aqueous solution of nickel(II) salt shows three absorbances, one of which has a value of ε = 2.95 dm-3 per mol per centimeter. What is the corresponding absorbance, if the path length of the solution cell used for the measurement is 1.00 cm? Write the value only.Tungsten hexacarbonyl (W(CO)6) is reacted with (EtC≡N) and the product is W(CO)3(N≡CEt)3.However, the product can be a mixture of fac and mer isomers. But a Chemist can determine fromanalysis of the infrared spectrum if the product is indeed a mixture of isomers or not. In thesynthesis experiment, the product shows 3 carbonyl stretching frequencies in the infraredspectrum, at 2021, 1898 and 1840 cm-1. Determine the irreducible representations of the stretchesexpected for each of the two species in their respective point group. Can you confirm what isomerwas isolated?What is the Nuclear Magnetic Resonance spectrum of CH3-CH(OCH2CH3)2
- What is the linearity (r-) value of the following concentration and absorbance values: SAMPLE CONCENTRATION ABSORBANCE 0.178 0.2127 0.274 0.2715 0.473 0.3892 0.574 0.4568 5 0.673 0.5327 0.864 0.6283 0.9876 O 0.9786 O 0.9562 O 0.9976Guanosine has a maximum absorbance of 275 nm. ϵ275= 8400M−1cm−1 and the path length is 1 cm. Using a spectrophotometer, you find the that A275=0.70. What is the concentration of guanosine?Predict 31PNMR spectrum of [Rh(PR3)Cl2]. Given phosphorus-31 is 100% abundant, rhodium is 100% abundant, all nuclear spins are (I=1/2).