R-carvone is responsible for the characteristic minty odor and flavor of spearmint oil, and its structure is shown below: H H-C₁-C₂ H H H CH C- sp² on C4 and sp² on C5 sp³ on C4 and sp² on C5 sp³ on C4 and sp³ on C5 sp² on C4 and sp³ on C5 C3- C H CAICS H H H H C6-H Which two orbitals overlap to form the o-bond between C4 and C5?
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- R-carvone is responsible for the characteristic minty odor and flavor of spearmint oil, and its structure is shown below: HIC :0 H H-C₁-C₂ H H C-CH O sp² on C5 and sp² on C6 O px on C5 and px on C6 O py on C5 and py on C6 O pz on C5 and pz on C6 O px on C5 and p, on C6 H CAC5 C3-CH H H H Which two orbitals overlap to form the T-bond between C5 and C6? Assume that all of C4 C5 and C6 lie in the xz plane. C6-HWhat are the relative energy levels of the three staggered conformations of 2,3-dimethylbutane when looking down the C2-C3 bond? Me Me H Me Me Me Me Me. Me Conformation: 191 1ක් පුදා H Me Me Me H H H A B C Me A is the highest energy conformation and C is the lowest (energy level of B is in between the two) O A and B are equal energy, and C is the highest energy conformation A and B are equal energy, and C is the lowest energy conformation C is the highest energy conformation and A is the lowest (energy level of B is in between the two) O B is the highest energy conformation and C is the lowest (energy level of A is in between the two)Nemotin is a compound that was first isolated from the fungi Poria tenuis and Poria corticola in the 1940s and was shown to possess potent antibacterial activity. (Org. Biomol. Chem. 2010, 8, 811-821). However, its structure was not verified until it was made in the laboratory much more recently. :ö H H-C-C-H H C=c=C H Nemotin Determine the hybridization state of each carbon atom in nemotin. ミ-0三O-O三
- Give the configuration of the substituents around double bond C in the structures below: В CH CH3 HO-CH2 A H но, CH2 D H3C CH CHECH2 H- CH2 CH2 но. ČH3 CH2-CH3 CH2 O A. E В.Z O C. Neitherd Which atom in the following structure has the incorrect number of bonds? H-CEC-C=C-H H-C=Ç-C+C-H HHH H-CÉC-C=C-H H H H H(càc-C=C-H нн H-C=C-CEC-H HH HWhat is the configuration, Z or E, of each of the following double bonds? (a) Br (b) Н Br (c) H H2C-CH3 (d) F 15NH2 С— C= H3C CI CI H3C CI CI H14N-CH3
- Esc smooth 0 CH₂- Ph -CH-CH3 (3) (CH3)3C-C=C—CH(CH3)CH₂CH3 CH3 5c CH₂-C=C-C-OH T CH₂CH3 CH3 C C-CH₂CH3 53-methyloct-4-yne H₂C CH3 H C=C-CH₂CH₂ CH3 -CBr₂ C=C-CH3 CH,–C=C–CH3 Ph-C=C-H (CH₂)₂C-C=C—CH(CH₂) CH₂CH3 Chapter 9 Alkynes Quiz 2 1. Name each molecule. 2. Use the molecules in the reactions 1 through 9 highlighted in red to determine the product. 3. Draw the line/angle or skeletal structure of eachmolecule. 4. Use the alkyne below to predict the products 1- 9.Compound C is? Compound C-DEPT 135 90 H3C I 70 CH3 CH 4 I 8 (ppm) CI CH₂CH₂CH-Cl CH₂ CH3 CH3-C-CH3 I Cl 1 I 30 10 CH3CH₂CH₂CH₂-ClGiven the following structure and numbering: H CO,H 3 H3C 1 A (a) Label the stereocenters of A as R or S and draw a Fischer Projection of the enantiomer of A with C1 on top and C4 on bottom. (b) Draw a Newman Projection of a diastereomer of 4 looking down the C2-C3 bond with C2 in front.