Q3/ A- What is the approximate M and N of 13% solution of H,SO, which has a specific gravity of 1.09 ? To what volume should 100 ml of the acid be diluted in order to prepare a 1.5N solution ? B- Define the buffer solution and find the pH of an acetic solution when 30 ml of 0.15 M NAOH have added to 50 ml of 0.IM HOAC.

Q3/ A- What is the approximate M and N of 13% solution of H,SO, which has a specific gravity of 1.09 ? To what volume should 100 ml of the acid be diluted in order to prepare a 1.5N solution ? B- Define the buffer solution and find the pH of an acetic solution when 30 ml of 0.15 M NAOH have added to 50 ml of 0.IM HOAC.

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter14: Equilibria In Acid-base Solutions

Section: Chapter Questions

Problem 60QAP: Consider an aqueous solution of HF. The molar heat of formation for aqueous HF is -320.1 kJ/mol. (a)...

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A solution is made by dissolving 15.0 g sodium hydroxide in approximately 450 mL water. The solution becomes quite warm, but after it is allowed to return to room temperature, water is added to bring the volume to 500.0 mL of solution. (a) Calculate the pH and pOH in the final solution. (b) Why would we wait for it to return to room temperature? (c) If the mass of the water used to initially dissolve the sodium hydroxide were exactly 450 g and the temperature of the water increased by 8.865 C, how much heat was given off by the dissolution of 15.0 g of solute? Assume the specific heat of the solution is 4.184 J/g. K. What is the molar heat change for the dissolution of sodium hydroxide (known as the enthalpy of solution, Hsol)?
Consider an aqueous solution of HF. The molar heat of formation for aqueous HF is -320.1 kJ/mol. (a) What is the pH of a 0.100 M solution of HF at 100C? (b) Compare with the pH of a 0.100 M solution of HF at 25C.
A diprotic acid, H2B(MM=126g/moL), is determined to be a hydrate, H2B xH2O. A 10.00-g sample of this hydrate is dissolved in enough water to make 150.0 mL of solution. Twenty-five milliliters of this solution requires 48.5 mL of 0.425 M NaOH to reach the equivalence point. What is x?
A friend asks the following: Consider a buffered solution made up of the weak acid HA and its salt NaA. If a strong base like NaOH is added, the HA reacts with the OH to form A. Thus the amount of acid (HA) is decreased, and the amount of base (A) is increased. Analogously, adding HCI to the buffered solution forms more of the acid (HA) by reacting with the base (A). Thus how can we claim that a buffered solution resists changes in the pH of the solution? How would you explain buffering to this friend?
For an aqueous solution of acetic acid to be called distilled white vinegar it must contain 5.0% acetic acid by mass. A solution with a density of 1.05 g/mL has a pH of 2.95. Can the solution be called distilled white vinegar?
How much solid NaCH3CO23H2O must be added to 0300 L of a 0.50-M acetic acid solution to give a buffer with a pH of 5.00? (Him: Assume a negligible change in volume as the solid is added.)
. How is the strength of an acid related to the fact that a competition for protons exists in aqueous solution between water molecules and the anion of the acid?
Water is accidentally added to 350.00 mL of a stock solution of 6.00 M HCI. A 75.00-mL sample of the diluted solution is titrated to pH 7.00 with 78.8 mL of 4.85 M NaOH. How much water was accidentally added? (Assume that volumes are additive.)
There is a buffer system in blood H2PO4 HPO42 that helps keep the blood pH at 7.40. (K aH2PO4 =6.2108). (a) Calculate the[ H2PO4 ]/[ HPO42 ] ratio at the normal pH of blood. (b) What percentage of the HPO42 ions are converted to H2PO4 when the pH is 7.00? (c) What percentage of the H2PO4ions are converted to HPO42 when the pH is 8.00?
For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.