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- Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.Compare the following conformers of butan-2-ol. Match each conformer to their corresponding relative energy. Recall, the more stable the conformer the lower the energy. 1. ОН CH3 CH3 H 2nd Highest Energy 2. HỌH CH3 2nd Lowest Energy H3C OH Highest Energy 3. H3C. CH3 Lowest Energy OH H. CH3 4. >
- 4. Draw the most stable chair conformation of the following disubstituted cyclohexane. Draw carefully positioned intersecting arcs to denote all sources of steric strain for this conformation. CH3 CH3Sight along the C2-C3 bond of 2-methylbutane. Arrange the following conformation from lowest to highest energy. CH3 H CH3 CH3 CH3 H CH3 H HCH; CH3 HH H CH3 ㄒH CH3 HWhich of the following is a Newman projection for the following compound as viewed down the indicated bond in the conformation shown? H. CH3 01 O II O III OIV Et CH3 1 Et H I CH3 13X Et CH3 -H || CH3 Et H CH3 Et Et ||| CH3 H H H CH3 Ø CH3 H CH3 IV
- Compare the following conformers of 1-fluoropropan-1-ol. Match each conformer to their corresponding relative energy. Recall, the more stable the conformer the lower the energy. OH CH3 'F 2. HOH 2nd Highest Energy H 2nd Lowest Energy H3C 3. H. ОН Lowest Energy H 'F Highest Energy ČH3 4. H3C, OH 'F 1. >4. Draw the most and least stable conformations of the following substituted cyclohexanes in the chair format (excluding transient conformations like half chair, twist boat and boat). Br BL Br BrThen draw the most stable and least stable Newman projection conformation from the C4-C5 bond in the molecule above
- Which of the following molecules will have the greatest difference in energy between its two chair conformations? Which of the following line structures is the same molecule as the Newman projection shown below? NOTE: The molecule may be in a different conformation that the one shown in the projection. A) Ô H. OH OH OH B) D) OH OHWhich conformation shown below is the most stable conformation of 2-methylbutane?2) Label the least favorable conformation and most favorable conformation of the substituted cyclohexane below. Explain your choices in 1-2 sentences or less. H3C H3C H3C F OH CH3 CH3 H3C CH3 F CH3 OH H3C CH3 H3C снаанз F CH3 CH3 -OH