PCl3 belong to C3V point group ?(b) Write down the totally symmetric representation of the point group of PCl3.(c) What is a symmetry-adapted linear combination of atomic orbitals?(d) Construct a linear-combination of 3s(Cl) atomic orbitals, ?1, such that ?1 belongs to the totallysymmetric representation of the point group of PCl3. (e) Construct a linear-combination of 3p(Cl) atomic orbitals, ?2, such that ?2 belongs to thetotally symmetric representation of the point group of PCl3.

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PCl3 belong to C3V point group ? (b) Write down the totally symmetric representation of the point group of PCl3. (c) What is a symmetry-adapted linear combination of atomic orbitals?

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.22E: Figure 13.27 shows the structure of the molecule porphine. Figure 13.27 The structure of porphine....

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Question

PCl3 belong to C_3V point group ?
(b) Write down the totally symmetric representation of the point group of PCl3.
(c) What is a symmetry-adapted linear combination of atomic orbitals?
(d) Construct a linear-combination of 3s(Cl) atomic orbitals, ?1, such that ?1 belongs to the totally

symmetric representation of the point group of PCl3.

(e) Construct a linear-combination of 3p(Cl) atomic orbitals, ?2, such that ?2 belongs to the

totally symmetric representation of the point group of PCl3.

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