On the first derivative of redox titration curve the end point can be more precisely located.     The volume on the x-axis corresponding to the peak of the curve is the end point of the titration.     The point on volume axis where the curve cuts through zero on the x-axis gives the end point.     The inflexion point/the steeply rising portion corresponds to the volume for the end point of the titration.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter15: Additional Aqueous Equilibria
Section: Chapter Questions
Problem 108QRT
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On the first derivative of redox titration curve the end point can be more precisely located.

   

The volume on the x-axis corresponding to the peak of the curve is the end point of the titration.

   

The point on volume axis where the curve cuts through zero on the x-axis gives the end point.

   

The inflexion point/the steeply rising portion corresponds to the volume for the end point of the titration.

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