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Indicate the mechanism of Hofmann degradation of the compound N-(2-phenylethyl)butan-1-
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- Below the incorrect mechanism for 2-methylocta-4,6-dien-1-amine write a discussion of the incorrect mechanism identifying all of the mistakes in the mechanism. Keep in mind that there will be more than one mistake in the given mechanism and that the product given is not necessarily the correct product of the reaction of your molecule with the given reagent. And For each mistake, give a detailed, scientific explanation of why it is incorrect.The following compounds are given to you:2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane(i) Write the compound which is most reactive towards SN2 reaction.(ii) Write the compound which is optically active.(iii) Write the compound which is most reactive towards P-elimination reaction.Amino acids are metabolized by a transamination reaction in which the amino group of the amino acid changes places with the keto group of an a-keto acid; the amino acid and a new a-keto acid. Draw the products of the transamination reaction between threonine and 2-oxopentanedioate. • You do not have to consider stereochemistry. • Use the charge tools to adjust the charges of the amine and carboxyl groups to the form in which they would be found at physiological pH. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ? √n [ Ⓡ ChemDoodle
- For the base-catalysed hydrolysis of 3-bromo-3-methylhexane (i.e. reaction with the nucleophile OH-): For the reaction intermediate, draw its structure and give the VSEPR description of the geometry at the reaction centre Give the names and draw the structures of the two reaction products. Explain your conclusions.In the reaction of trans-cinnamaldehyde under the conditions of 2-propanol and gamma-Al2O3, the product yielded is cinnamyl alcohol. When the reaction was first performed the GC and IR showed signals of the formation of a carbocation-like intermediate on the phenyl ring. The 2-propanol used contained high amounts of HCl. How does the high amount of HCl in 2-propanol affect gamma-Al2O? Also, show the intermediate that was formed? The second reaction performed did not contain high amounts of HCl so the product formed was cinnamyl alcohol. Draw the proton NMR spectrum of cinnamyl alcohol.Give the structure of hydrocarbons that yield CH3CH2COCH3 upon ozonolysis.
- 1) Based on the Material Safety Data Sheets (MSDS) for the compounds, which of the compounds in this experiment is the most hazardous, and why (you have been given a representative aryl halide rather than all of the alkenes – as the products are all new, there’s not a simple answer to gauge their potential hazard)? 2,3-dihydrofuran,2-Mercaptobenzimidazole,Selectfluor, Dimethylformamide,dichloromethane-methylene chloride.(b) The activating and deactivating groups could affect the position(s) of the next incoming group(s) to the benzene ring. Based on the structure below, analyze and explain the group(s) on the benzene ring is activating or deactivating group. Then, identify the product(s) formed from the following reactions. NH, CC, CH;CH,COCI AICI, (i) NH, HNO, H,SO, (ii) H Br AICI, (iii) Page 3 of 4Write the reaction for the formation of the 2,4-DNP derivative of butanal (C3H¬CHO)
- Following compounds are given to you:2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane(i) Write the compound which is most reactive towards SN2 reaction.(ii) Write the compound which is optically active.(iii) Write the compound which is most reactive towards β – elimination reactionwrite the mechanism of the reaction when (R)-2-bromo-2-methylpropane is reacted with NaI.Treatment of pentanedioic (glutaric) anhydride with ammonia at elevated temperature leads to a compound of molecular formula C5H7NO2. What is the structure of this product? [Hint: You need to think about the reactivity not only of acid anhydrides but also of amides and carboxylic acids]