In the reactionNH4*(aq) + H₂O(l) → NH3(aq) + H₂O*(aq)the conjugate acid-base pairs are...O A. NH4*/H₂O and NH3/H3O*O B. NH4*/NH3 and H3O*/H₂OO C. NH4+/H3O* and H₂O/NH3OD. NHÀ/H2O

Acid and Base: Acid: acids are proton (H+) donor. Base: bases are proton (H+) acceptor. Conjugate…

In the reaction NH4*(aq) + H₂O(l) →→ NH3(aq) + H₂O*(aq) the conjugate acid-base pairs are... O A. NH4+/H₂O and NH3/H3O* B. NH4*/NH3 and H3O*/H₂O C. NH4+/H3O* and H₂O/NH3 D. NH4*/H₂O

In the reaction NH4(aq) + H₂O(l) →→ NH3(aq) + H₂O(aq) the conjugate acid-base pairs are... O A. NH4+/H₂O and NH3/H3O* B. NH4/NH3 and H3O/H₂O C. NH4+/H3O* and H₂O/NH3 D. NH4*/H₂O

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter12: Chemical Equilibrium

Section: Chapter Questions

Problem 12.62PAE: 12.62 Write the formula of the conjugate acid of each of the following bases, (a) OH-, (b) NHj, (c)...

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Students are often surprised to learn that organic acids, such as acetic acid, contain OH groups. Actually, all oxyacids contain hydroxyl groups. Sulfuric acid, usually written as H2SO4, has the structural formula SO2(OH)2, where S is the central atom. Identify the acids whose structural formulas are shown below. Why do they behave as acids, while NaOH and KOH are bases? a. SO(OH)2 b. ClO2(OH) c. HPO(OH)2
Most naturally occurring acids are weak acids. Lactic acid is one example. CH3CH(OH)CO2H(s)+H2O(l)H3O+(aq)+CH3CH(OH)CO2(aq) If you place some lactic acid in water, it will ionize to a small extent, and an equilibrium will be established. Suggest some experiments to prow that this is a weak acid and that the establishment of equilibrium is a reversible process.
Consider a solution prepared by mixing a weak acid HA. HCl, and NaA. Which of the following statements best describes what happens? a. The H+ from the HCl reacts completely with the A from the NaA. Then the HA dissociates somewhat. b. The H+ from the HCl reacts somewhat with the A from the NaA to make HA, while the HA is dissociating. Eventually you have equal amounts of everything. c. The H+ from the HCl reacts somewhat with the A from the NaA to make HA while the HA is dissociating. Eventually all the reactions have equal rates. d. The H+ from the HCl reacts completely with the A from the NaA. Then the HA dissociates somewhat until too much H+ and A are formed, so the H+ and A react to form HA, and so on. Eventually equilibrium is reached. Justify your choice, and for choices you did not pick, explain what is wrong with them.
Strong Acids, Weak Acids, and pH Two 0.10-mol samples of the hypothetical monoprotic acids HA(aq) and HB(aq) are used to prepare 1.0-L stock solutions of each acid. a Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c Say that the HA(aq) solution has a pH of 3.7. Is this the stronger of the two acids? How did you arrive at your answer? d What is the concentration of A(aq) in the HA solution described in part c? e If HB(aq) is a strong acid, what is the hydronium-ion concentration? f In the solution of HB(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), B(aq), HB(aq), or OH(aq)? How did you decide? g In the solution of HA(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), A+(aq), HA(aq), or OH(aq)? How did you decide? h Say you add 1.0 L of pure water to a solution of HB. Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i You prepare a 1.0-L solution of HA. You then take a 200-mL sample of this solution and place it into a separate container. Would this 200 mL sample be more acidic, be less acidic, or have the same acidity as the original 1.0-L solution of HA(aq)? Be sure to support your answer.
12.62 Write the formula of the conjugate acid of each of the following bases, (a) OH-, (b) NHj, (c) CHjNHt, (d) HPO/-, (e) CO.,2’
You have a solution of the weak acid HA and add some HCl to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
A solution of sodium cyanide, NaCN, has a pH of 12.10. How many grams of NaCN are in 425 mL of a solution with the same pH?
Assuming that the conductivity of an acid solution is proportional to the concentration of H3O+, sketch plots of conductivity versus concentration for HCl and HF over the 0- to 0.020 M concentration range.
Consider a 0.33 M solution of the diprotic acid H2X. H2X H+(aq)+ HX(aq)Ka1=3.3 10 4 HX H+(aq)+ X2(aq)Ka2=9.7 10 8 Calculate the pH of the solution and estimate [HX-] and [X2-].
For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.
For conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)
Composition diagrams, commonly known as alpha plots, are often used to visualize the species in a solution of an acid or base as the pH is varied. The diagram for 0.100 M acetic acid is shown here. The plot shows how the fraction [alpha ()] of acetic acid in solution, =[CH3CO2H][CH3CO2H]+[CH3CO2] changes as the pH increases (blue curve). (The red curve shows how the fraction of acetate ion, CH3CO2, changes as the pH increases.) Alpha plots are another way of viewing the relative concentrations of acetic acid and acetate ion as a strong base is added to a solution of acetic acid in the course of a titration. (a) Explain why the fraction of acetic acid declines and that of acetate ion increases as the pH increases. (b) Which species predominates at a pH of 4, acetic acid or acetate ion? What is the situation at a pH of 6? (c) Consider the point where the two lines cross. The fraction of acetic acid in the solution is 0.5, and so is that of acetate ion. That is, the solution is half acid and half conjugate base; their concentrations are equal. At this point, the graph shows the pH is 4.74. Explain why the pH at this point is 4 74.