In an unprecedented initiative, the professor chose you to carry out the determination of a special sample in order to verify the inherent indication system. For that, an aliquot of 25.00 mL of a solution containing Fe(III) salts was titrated with EDTA 0.00982 mol/L, using potassium thiocyanate as indicator. In this case, you have found the volume of 31.10 mL of titrant to End Point. Based on the information given in the table, choose the option that best describes/explains the process linked to the indication system of the Final Point of the degree: (a) The indication of the system will be given by the disappearance of the reddish coloration, due to the displacement reaction: Fe(III) complex with EDTA is formed in detriment of the Fe(III) complex with thiocyanate. (b) The indication of the system will be given by the appearance of a reddish color, in function of the displacement reaction: Fe(III) complex with thiocyanate is formed in detriment of the Fe(III) complex with EDTA. (c) The indication of the system will be given by the appearance of the reddish coloration, in function of the displacement reaction: Fe(III) complex with EDTA is formed in detriment of the Fe(III) complex with thiocyanate. (d) The indication of the system will be given by the disappearance of the reddish coloration, due to the displacement reaction: thiocyanate complex with EDTA is formed in detriment of the Fe(III) complex with thiocyanate.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter19: Complex Ions
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In an unprecedented initiative, the professor chose you to carry out the determination of a special sample in order to verify the inherent indication system. For that, an aliquot of 25.00 mL of a solution containing Fe(III) salts was titrated with EDTA 0.00982 mol/L, using potassium thiocyanate as indicator. In this case, you have found the volume of 31.10 mL of titrant to End Point. Based on the information given in the table, choose the option that best describes/explains the process linked to the indication system of the Final Point of the degree:

(a) The indication of the system will be given by the disappearance of the reddish coloration, due to the displacement reaction: Fe(III) complex with EDTA is formed in detriment of the Fe(III) complex with thiocyanate.

(b) The indication of the system will be given by the appearance of a reddish color, in function of the displacement reaction: Fe(III) complex with thiocyanate is formed in detriment of the Fe(III) complex with EDTA.

(c) The indication of the system will be given by the appearance of the reddish coloration, in function of the displacement reaction: Fe(III) complex with EDTA is formed in detriment of the Fe(III) complex with thiocyanate.

(d) The indication of the system will be given by the disappearance of the reddish coloration, due to the displacement reaction: thiocyanate complex with EDTA is formed in detriment of the Fe(III) complex with thiocyanate.

Complex
Fe(SCN)
Fe(llI)-EDTA 1,3 x 1025 | colorless
KE
color
8,9 x 102
red
M.A. (Fe) = 55,84 g/mol
Transcribed Image Text:Complex Fe(SCN) Fe(llI)-EDTA 1,3 x 1025 | colorless KE color 8,9 x 102 red M.A. (Fe) = 55,84 g/mol
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