in a much lower ratio [Reaction 2, 55:45 ratio]. What is the major product for reaction 1? OtBu= 0 H₂C CH₂ CH₂ H₂C CHI to HỔ OtBu Ll CH₂ OIBU Product 1 + H₂C CH₂ OtBu Product 2 Reaction 1 99.1

in a much lower ratio [Reaction 2, 55:45 ratio]. What is the major product for reaction 1? OtBu= 0 H₂C CH₂ CH₂ H₂C CHI to HỔ OtBu Ll CH₂ OIBU Product 1 + H₂C CH₂ OtBu Product 2 Reaction 1 99.1

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.SE: Something Extra

Problem 30MP: The carbocation electrophile in a Friede1-Crafts reaction can be generated by an alternate means...

See similar textbooks

Related questions

Q: Question 16: Consider the following reaction: 2 N₂0(g) - > 2 NO(g) +O₂(g). The rate law is: rate =…

A: For a first-order reaction: Half-life = 0.693/rate constant

Q: Which one should be considered the major thermodynamic product of the following reaction? OH H₂O+ OH…

Q: Calculate the pH of a 1.00 L buffer solution containing 0.155 mol of acetic acid (HC₂H₂O₂) and 0.186…

A: For buffer solution,Henderson equation is When HCl added then salt (sodium acetate) react with HCl…

Q: The equilibrium constant, K., for the following reaction is 5.40 at 346 K: COBr₂(g) →CO(g) + Br₂(g)…

A: Answer:For any reaction value of equilibrium constant KP is equal to the ratio of partial pressure…

Q: 9. On the basis of molecular orbital theory and Hckel's rule, which of these compounds should be…

A: Alternate double bonds which should obey (4n+2)π ( n=1,2,3,4..) electron rule.It should be…

Q: Question 3: Consider the reaction 4 A + 3 B-> 2 C The initial concentration of A and B are both…

A: Given reaction 4 A + 3 B -------> 2 CThe initial concentration of A = 0.100 MThe initial…

Q: 180 Mass Spec 160 Relative Intensity 100 80 60 40- 20- 0 140 MS-NU-1535 25 120 50 100 PPM 75 80 m/z…

Q: Verify your molar absorptivity value. Did you report your data to the correct number of significant…

A: We have to verify the molar absorptivity value.

Q: Figure 4 Potential energy HAL Reaction progress Using Figure 4, drag the letters into the correct…

Q: Compare the CsCl and CaF2 lattices. 1. Which of the Bravais lattices does each structure exhibit?…

Q: 4. For the following molecule draw a Lewis dot structure. Then indicate the atomic orbitals on each…

A: Lewis Structures: Lewis structures are diagrams that represent the bonding between atoms in a…

Q: I (a) Provide suitable organic and/or inorganic reagents for the transformation of 1 to 2 below.…

A: Kinetic enolate is that enolate which is the result of abstraction of acidic proton from less…

Q: For the following reaction: 2N2O5(g) ---> 4 NO2(g) + O2(g) The rate law is first order with…

A: The rate constant for the first order reaction (k) = 4.82 x 10-3 sec-1 The initial concentration of…

Q: Write the formula for copper (1) phosphide G Write the formula for copper (1) phosphide Show…

A: We are going to determine the formula of copper (I) phosphide.

Q: For the following solutions, draw molecular level representations that clearly show the strongest…

Q: ball & stick I Which of the following represent structural isomers of the molecule shown in the…

A: Structural isomer

Q: Arrange in order of decreasing acidity: i Hy/2CHOPh. CH₂CH₂NO₂, (CH₂)₂CHCPH, CH₂CH₂CN, CH₂(CN)₂ (a)…

A: Since you have posted a question with multiple sub parts, we will provide the solution only to the…

Q: MISSED THIS? Read Section 14.6 (Page); Watch KCV 14.6, IWE 14.9. A glucose solution contains 65.6 g…

A: To determine the boiling point elevation of a solution, you can use the formula:ΔTb = kb *…

Q: Determine the amount of Cd²+ per gram of dry clam. Express your final result as milligrams of…

A: Varying amounts of Cd2+ standard solution of concentration (84.0 ppb/L) were added to unknown sample…

Q: We can describe the combustion of glucose, and the accompanying energy change, as. C6H12O6+602-6H₂O…

A: To express the molar energy change in terms of oxygen consumed, we need to calculate the energy…

Q: a. b. CI ОН 0 Br ОН Br ОН CI ОН

A: Now, let's consider pairs of molecules and determine whether they are identical, enantiomers, or…

Q: The preparations of two aqueous solutions are described in the table below. For each solution, write…

A: Given,0.1 mol of HI is added to 1.0 L of a 0.8 M NH3 solution acids: bases: other:0.50 mol of HI is…

Q: The rate of a certain reaction is given by the following rate law: rate == e=k[H₂] [¹₂] 4 Use this…

A: Rate of a certain reaction is rate = k [H2] [I2] At a certain concentration of H2 the rate of this…

Q: 3. If you have a solution that is 0.001 M carbonate (CO), to what concent concentration of Ag" be…

Q: For the following reaction: H2(g) + ICl(g) ----> HI(g) + HCl(g) slow HI(g) + ICl(g) ---> I2(g) +…

A: Rate law equation

Q: Suppose 4.32 g of nickel(II) iodide is dissolved in 350. mL of a 47.0 m M aqueous solution of…

A: The balanced equation for the reaction between Nickel(II) iodide and potassium carbonate is NiI2…

Q: 2. The analytical ability of two lab technicians was compared by having each perform analyses for…

A: Given DataAnalyst As.d = 0.12 %N=6Analyst Bs.d. =0.06 %N=5To determine:whether these results suggest…

Q: [A] M 0.200 0.200 0.400 The order in A is The order in B is k= O k=[A]²[B] Ok=[A][B]² [B] M O…

Q: A robot spacecraft returned samples from the planetesimal 98765 ALEKS, located in the outer Solar…

A: We have been provided with data from mass-spectroscopic analysis, including the masses of ruthenium…

Q: Provide the correct IUPAC name for the skeletal (line-bond) structure shown here. 3,3- x 3,3-di…

A: The question is based on the concept of IUPAC nomenclature.To write IUPAC name of given compound…

Q: You are titrating a 0.1 M 100 mL sample of NaOH with1.0M HBr. Find the pH at 3, 5, 7, 11, 15 mL of…

A: Given,Molarity of NaOH = 0.1 MVolume of NaOH = 100 mLMolarity of HBr = 10 MVolumes of HBr = 3 mL, 5…

Q: Estimate the ratio of the axial to equatorial form of 1-chlorocyclohexane at room temperature

A: The “A-value” is a good tool to understand how much the substituent, costs to go to most stable…

Q: Draw a mechanism for this reaction: H₂C CH3 D-CI CH3

Q: When metal zinc reacts with hydrochloric acid, what are the final products? Zn(s) + HCI(aq) → H (g)…

A: When the acids react with metals results in the formation of a salt. Along with salt, the hydrogen…

Q: 100.00 mL of 2000ppm NaCI stock solution. -2.0319g of NaCI weighed out What is the exact…

A: To find the exact concentration of the stock solution in %w/v (mass/volume) and molarity (M), we can…

Q: Assume that you have a cubic unit cell in which you can fit exactly 8 atoms as shown below (ALL 8…

A: In a crystal lattice, the smallest continual unit is called unit cell. It explain the structure of a…

Q: Draw the two major organic products of the following reaction. گہر OH conc. HBr

A: Addition of follows Markovnikov's addition, i.e., when is added to an unsymmetrical alkene,…

Q: Draw Newman projections of 2,3-dibromopentane through C2- C3 bond.

A: Structure: We have to draw the Newman projection through the C2-C3…

Q: Draw the skeletal structure(s) of the major product(s) of the reaction below. HO NO ₂ HNO3 H₂SO4

A: In this question asking the product

Q: Oxides of virtually every element are known. Bromine, for example, forms several oxides when treated…

A: In the given question we have to calculate the formula of the compound by using mole ratio.…

Q: Emission of beta particles in a radioactive decay results in a product of Choose one of the…

A: Beta Particles: Beta particles are high-energy electrons (β⁻) or positrons (β⁺) emitted from a…

Q: Please select ALL plausible Lewis Dot structures which are theoretically possible. Note: This…

A: ll

Q: What is the product of the following reaction? Cl A) c) NO₂ Cl CH3O'Na CH3OH OCH3 OCH3 NO₂ B) D) ОН…

A: Aryl halides can undergo nucleophilic aromatic substitution reaction if an electron withdrawing…

Q: Draw the major organic product of the following reaction sequence. ? 1) RCO3H 2) NaSMe 3) H₂O+

Q: [References] The following alkene is treated with one equivalent of NBS in CH₂ Cl2 in the presence…

A: NBS is a reagent used for allylic bromination. In the presence of NBS reagent, bromination takes…

Q: What is the rate law for the following reaction? Ph- Br rate = k[R-OH] rate = k[R-Br][R] rate = Ksp…

A: Given question related to expressing rate law for the given nucleophilic substitution reaction.

Q: Suppose 1.66 g of barium nitrate is dissolved in 250. mL of a 41.0 m M aqueous solution of sodium…

A: The balanced equation is Ba(NO3)2 (aq) + Na2CrO4 (aq) -------> BaCrO4 (s) + NaNO3 (aq) The net…

Q: ORT MARY Mass or cyclohexane collected (g) Vapor temperature when distillation of toluene started:…

Q: 1. How many moles of butane, C4H10(l), must be burned to produce 182 kJ of heat under standard…

A: We have to find how many moles of butane, C4H10(l), must be burned to produce 182 kJ of heat under…

Q: Solubility and Precipitation Reactions Determine if each compound shown is soluble or insoluble.…

A: Answer:All the given compounds are inorganic compounds and solubility of inorganic compounds depends…

Question

Electrophilic addition of hydroiodic acid to (3S)-3-tert-
butoxypent-1-ene gives an unequal mixture of two products
[Reaction 1, 99:1 ratio]. The same reaction carried out on
(3S)-3-methoxy-pent-1-ene also gave two stereoisomers albeit
in a much lower ratio [Reaction 2, 55:45 ratio]. What is
the major product for reaction 1?
0
HỌC LỊCH
CH₂
OtBu =
o
OCH₂=CH₂
Product 2
Product 1
H₂C
H₂C
Y CH₂
OtBu
CH₂H₂C
CH₂
OCH,
HI
ECO
Ⓒ1Bu
Product 1
H₂C
CH₁₂ H₂C
H
+
OCH₂
Product 3
CH₂
CH₂
OtBu
Product 2
H₂C T
CH₂
OCH,
Product 4
Reaction 1
99:1
Reaction 2
50:45

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1: Introduction

VIEW

Step 2: Solution

VIEW

Solution

VIEW

Step by step

Solved in 3 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The product below can be prepared from cyclohexanone through the following reaction sequence? A) [1] (CH3CH2)2NH, mild acid; (2) CH3CH2CH2BR; (3] HCI, H20 B) [1] CH3CH2NH2, mild acid; [2] CH3CH2CH2Br; [3] HCI, H20 ) [1] CH3OH, H+; [2] CH3CH2CH2MgBr; [3] HCI, H20 D) [1] nBuLi; (2] CH3CH2CH2Br: (3] ETNH2, mild acid E) [1] nBuLi: (2] CH3CH2CH2Br; (3] Et2NH, mild acid
Propose a pericyclic mechanism to account for the following transformation:
The following equation shows the reaction of trans-2,3-diphenyloxirane with hydrogen chloride in benzene to form 2-chloro-1,2-diphenylethanol. (a) How many stereoisomers are possible for 2-chloro-1,2-diphenylethanol? (b) Given that opening of the epoxide ring in this reaction is stereoselective, predict which of the possible stereoisomers of 2-chloro-1,2-diphenylethanol is/are formed in the reaction.
Acid-catalyzed hydrolysis of the following epoxide gives a trans diol. Of the two possible trans diols, only one is formed. How do you account for this stereoselectivity?
Give strucutre of products formed including stereochemistry if appropriate. If more than one product is formed, indicated which is the major product or if formed in equal amounts. PhMgBr (2 equiv.) then H30* HO, он он РСС но
Addition of hydrochloride acid to 1-isopropenyl-1-methylcyclopentane generates 1-chloro-1,2,2 trimethylcyclohexane. Draw the complete mechanism, including intermediates, to illustrate electron flow in the reaction.
What products would ypu obtain from reaction of 2,4-dimethyl-2-pentene with BH3, followed by H2O2, OH-? Show its complete reaction mechanism.
Provide a mechanism with products for the reaction above. CH3 2Na/Liq.NH₂
3. Propose a plausible mechanism for the following transformation: & Q & CF3 H₂N CN 'N CF HOH
Draw the SNl or SN2 reaction with CN for the following molecules t butylchloride , n - butylbromide , 2 -bromobutane . Explain in which mechanism it will react and why ?
A good Williamson synthesis of ethyl methyl ether would beCH3CH2¬O- Na+ + CH3I ¡ CH3CH2¬O¬CH3 + NaIsodium ethoxide methyl iodide ethyl methyl etherWhat is wrong with the following proposed synthesis of ethyl methyl ether? First, ethanolis treated with acid to protonate the hydroxy group (making it a good leaving group), andthen sodium methoxide is added to displace water.CH3CH2(incorrect synthesis of ethyl methyl ether)OH + H+ CH3CH2 OH2+CH3CH2 O CH3
The two pentene isomers react with mCPBA, followed by an aqueous workup with NaOH/H2Ó. Draw the key reaction intermediates and the product(s); use arrow pushing to explain the stereochemical outcomes of the reactions Intermediate Final Products MCPBA CO2OH mCPBA NaOH/H2O CI Intermediate Final Products MCPBA NaOH/H2O 6.