If you have 6.61 g of caffeine dissolved in 72.3 mL of water and the extraction coefficient between H2O and CH2Cl2 is 21.51. How many grams of caffeine will extract into the CH2Cl2 layer if you add 87.6 mL?
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If you have 6.61 g of caffeine dissolved in 72.3 mL of water and the extraction coefficient between H2O and CH2Cl2 is 21.51. How many grams of caffeine will extract into the CH2Cl2 layer if you add 87.6 mL?
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- Oral rehydration salts are stated to contain the following components: Sodium Chloride 3.5g Potassium Chloride 1.5g Sodium Citrate 2.9g Anhydrous Glucose 20.0g 8.342 g of oral rehydration salts are dissolved in 500 ml of water. 5 ml of the solution is diluted to 100 ml and then 5 ml is taken from the diluted sample and is diluted to 100 ml. The sodium content of the sample is then determined by flame photometry. The sodium salts used to prepare the mixture were: Trisodium citrate hydrate (C6H5Na3O7, 2H2O) MW 294.1 and sodium chloride (NaCl) NW 58.5. Atomic weight of Na = 23. The content of Na in the diluted sample was determined to be 0.3210 mg/100 ml. Determine the % of stated content of Na in the sample.A 1 mL sample of glycogen was calculated to contain 21 µmol (micromole) glucose. To 1 mL of this sample was added 2 mL of 2 M HCl. It was then hydrolysed by boiling the solution for 15 minutes. After boiling the hydrolysate was cooled and made up with H2O to a final volume of exactly 10 mL. The glucose was measured in this solution and found to have a concentration of 340 µg/mL (microgram/milliliter). i) Calculate the mass (mg) of glucose in the 10 mL of hydrolysate. As the 1 mL of glycogen sample was made up to a final volume of 10 mL, this mass of glucose was produced by the hydrolysis of the original 1 mL glycogen sample. ii) Calculate the amount (µmol) of glucose produced by the hydrolysis of the glycogen sample. iii) Calculate the purity of the glycogen used in the sample as % Purity = (moles of measured glucose/ moles of calculated glucose in glycogen) *100 iv) state your answer in a complete sentence. Show your working out such that the marker can easily understand it.…A 1 mL sample of glycogen was calculated to contain 35 µmol (micromole) glucose. To 1 mL of this sample was added 2 mL of 2 M HCL. It was then hydrolysed by boiling the solution for 15 minutes. After boiling the hydrolysate was cooled and made up with H2O to a final volume of exactly 10 mL. The glucose was measured in this solution and found to have a concentration of 570 µg/mL (microgram/milliliter). i) Calculate the mass (mg) of glucose in the 10 mL of hydrolysate. As the 1mL of glycogen sample was made up to a final volume of 10 mL, this mass of glucose was produced by the hydrolysis of the original 1 mL glycogen sample. ii) Calculate the amount (µmol) of glucose produced by the hydrolysis of the glycogen sample. iii) Calculate the purity of the glycogen used in the sample as % Purity = (moles of measured glucose/ moles of calculated glucose in glycogen) *100 iv) state your answer in a complete sentence.
- 5.0 mL of 1-butanol was mixed with 10 mL of HCl. The reaction was put on an ice bath and 4 mL of concentrated sulfuric acid was added. This mixture was refluxed for 45 min and then the product was co-distilled with water using a simple distillation apparatus. Water and the product are immiscible. 1-butanol has a molar mass of 74.12 g/mol, a density of 0.810 g/mL, and a boiling point of 118 C. The product has a molar mass of 92.57 g/mol, a density of 0.880 g/mL, and a boiling point of 78 C. What is the nucleophile in this reaction? What is the role of H2SO4 in this reaction? Calculate the theoretical yield for this reaction. Give your answer in grams. Select the following statements that can be said about the reaction shown.Hypothetical solubility data for compound A. Solubility in Boiling Solvent 0.3 g/100 mL 10 g/100 mL 4 g/100 mL 3 g/100 mL Solubility in cold Solvent 0.02 g/100 mL 9 g/100 mL 0.2 g/100 mL 0.3 g/100 mL Solvent Hexanes Ethanol Water Methanol Chose the best solvent to purify 2 g of compound A by crystallization. Methanol Ethanol Hexanes WaterWhy do two layers form when solutions containing water are added to the extracted dichloromethane (CH2CI-2) solution?
- Table 1. Solubility Tests. Functional Group Observations (specify type if any) Sample in concentrated (+/-) H2SO4 Color orange Hydroxyl group Hydroxyl group Hydroxyl group 1-butanol Color orange 2-butanol Color orange diisopropyl ether Look at the structures of compounds tested for solubility in concentrated H2SO4. What generalization can be made for a substance to be soluble in concentrated H2SO4 ?Tea leaves were boiled in water and around 1.50 gram of caffeine were extracted by 200.0 mL of water. If three portions of 25.0 mL of dichloromethane were used to extract the caffeine from the aqueous layer, how much caffeine will be extracted by the dichloromethane? Solubility of caffeine in water: 2.18 g per 100 mL waterSolubility of caffeine in dichloromethane: 18.2 g per 100 mL dichloromethaneDetermine the mole fraction of p-dichlorobenzene dissolved in 1.00L of cyclohexane that shifts the vapor pressure from 78mmHg to 70 mmHg. Can you determine the mass of solute dissolved?
- A sample containing chlorophenol, C6H4ClOH, was analysed by gravimetric analysis. A 0.783-g of this sample goes through a chemical process allowing the chlorine in the chlorophenol to precipitate as silver chloride, weighing 0.271 g. Calculate the % (wt/wt) of the chlorophenol in the sample, assuming that chlorophenol is the only source of chlorine in the sample. Provide your answer to two decimal places and without units. Avoid using scientific notation.The distribution coefficient (K) of formic acid (HCO2H) in 1-octanol versus water is 0.39. If a solution of 4.00 grams of formic acid in 100.00 mL of 1-octanol is extracted with one 10.00 mL portion of water, how many grams (to the hundredths place) will remain in the organic layer?Tea leaves were boiled in water and around 1.50 grams of caffeine were extracted by 200.0 mL of water. If three portions of 25.0 mL of dichloromethane were used to extract the caffeine from the aqueous layer, how much caffeine will be extracted by the dichloromethane? Solubility of caffeine in water: 2.18 g per 100 mL waterSolubility of caffeine in dichloromethane: 18.2 g per 100 mL dichloromethane