If the over-all equilibrium constant (Koa) for the Ag(NH3)2* formation in an AgCl solution is equal Ksp X Kf, calculate pKoa if K, is 1.8 x 10-10. sp

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter14: Chemical Equilibrium
Section: Chapter Questions
Problem 14.70QE
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Based on the first picture, answer the question on the second picture.

If the over-all equilibrium constant
(Koa) for the Ag(NH3),* formation in
an AgCl solution is equal Ksp x Kf,
calculate pKoa if Ksp is 1.8 x 10-10.
Transcribed Image Text:If the over-all equilibrium constant (Koa) for the Ag(NH3),* formation in an AgCl solution is equal Ksp x Kf, calculate pKoa if Ksp is 1.8 x 10-10.
Formation of soluble silver-ammonium complex, in an
AgCl solution, occurs in a 3-step process:
AgCI(s)= Ag* (aq) + CH(aq)
Ksp
Ag*(aq) + NH3(aq) = AGNH3*(aq)
K,
AGNH3*(aq) + NH3(aq)= Ag(NH3)2"(aq) K2
where Kp is the solubility product for AgCl and K, & K2
are the equilibrium constants for the complex formation.
The over-all formation constant (K;) for the Ag(NH3)2*
complex is equal to K, x K2.
Transcribed Image Text:Formation of soluble silver-ammonium complex, in an AgCl solution, occurs in a 3-step process: AgCI(s)= Ag* (aq) + CH(aq) Ksp Ag*(aq) + NH3(aq) = AGNH3*(aq) K, AGNH3*(aq) + NH3(aq)= Ag(NH3)2"(aq) K2 where Kp is the solubility product for AgCl and K, & K2 are the equilibrium constants for the complex formation. The over-all formation constant (K;) for the Ag(NH3)2* complex is equal to K, x K2.
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