i) You did the following reaction, worked up in Ethyl Acetate and Water. ၀ Did your reaction work? What are the extra peaks in the NMR spectrum? 10 Chem Shift 1.27 2.03 2.35 3.65 4.15 4.61 5.28 7.11 7.25 9.54 NaBH₂ CH₂Cl₂ solvent Integral 0.036 0.035 1.53 0.50 0.023 1.03 0.005 1.01 1.05 0.003 OH Multiplicity triplet singlet singlet singlet (removed by D20 shake) quartet singlet PPM singlet doublet doublet singlet

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter19: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 19.21QAP
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i) You did the following reaction, worked up in Ethyl Acetate and Water.
NaBH
6=6
CH₂Cl₂ solvent
Did your reaction work? What are the extra peaks in the NMR spectrum?
10
Chem Shift
1.27
2.03
2.35
3.65
4.15
4.61
5.28
7.11
7.25
9.54
Integral
0.036
0.035
1.53
0.50
OH
0.023
1.03
0.005
1.01
1.05
0.003
Multiplicity
triplet
singlet
singlet
singlet (removed by D20 shake)
quartet
singlet
singlet
doublet
PPM
doublet
singlet
Transcribed Image Text:i) You did the following reaction, worked up in Ethyl Acetate and Water. NaBH 6=6 CH₂Cl₂ solvent Did your reaction work? What are the extra peaks in the NMR spectrum? 10 Chem Shift 1.27 2.03 2.35 3.65 4.15 4.61 5.28 7.11 7.25 9.54 Integral 0.036 0.035 1.53 0.50 OH 0.023 1.03 0.005 1.01 1.05 0.003 Multiplicity triplet singlet singlet singlet (removed by D20 shake) quartet singlet singlet doublet PPM doublet singlet
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