Give the equation for the complete titration of aspartic acid with a base, NaOH. At what pH, can you use aspartate solution a buffer?
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- Consider the following pH titration curve of a diprotic acid. What is the approximate values for pka 1 and pka 2? the curve is attached below.Glycine hydrochloride (Cl− H3N+CH2COOH) is a diprotic acid that contains a carboxylic acid group and an ammonium group and is therefore called an amino acid. It is often used in biochemical buffers. Solve, In analogy with Figure , sketch the titration curve of this diprotic acid.Refer to the following titration curve below: 13 12 11 10 9 7 6 5 4 3 4 6 8 10 12 14 16 18 20 22 24 26 28 30 Volume of Titrant / mL - Unknown Acid 0.10 mol/L - titrant = NaOH 0.1 mol/L At ph 10.0, which form of histidine is most abundant? His2+ His- His° His+
- Using this data, calculate the molarity of the oxalic acid standard solution.Given the titration curve of the hypothetical polyprotic acid X at 0.100 M concentration (pKa1=4.0, pKa2=8.0, pKa3=12.0) titrated with 0.600 M NaOH, identify the pH at point C, H, E, and M.A base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 88 of the manganese has precipitated? Table 5-7 Solubility-Product Constants, K, at 25°C Fluorides Chromates (cont.) Ag, Cro, PbCro, Hydroxides (cont) Ni(OH), Zn(OH), Cu(OH), Hg(OH), Sn(OH), Cr(OH), A(OH), BaF, MgF, PbF, SrF, CaF, 2.4 x 10-5 X 10-8 x 10-8 1.9 x 10-12 1.6 x 10-16 4.5 X 10-17 1.6 x 10-19 3 2 x 10-16 4 Carbonates 7.9 x 10-10 3.9 x 10-11 X 10-26 NiCO, CaCO, BaCo, SrCO, CuCO, ZnCO, MnCO, 1.4 x 10-7 3 10-27 4.7 x 10- 6.7 x 5 x 6 x 10-38 2.5 x 10-43 Chlorides 10-31 1.6 x 10- 1.7 x 10-10 1.1 x 10-18 1.6 x 10-9 7 x 10-10 2.5 x 10-10 10-33 PBCI, AgCi Hg,Cl, Fe(OH), Co(OH), Sulfides 2 x 10-10 8.8 x 10-11 2.1 x 10-11 Bromides X 10-16 X 10-19 3 x 10-21 X 10-22 2.5 x 10-22 X 10-26 1.0 x 10-28 MnS 7. PbBr, AgBr Hg, Br, 4.6 x 10-6 5.0 x 10-13 Feco Ag,CO, CdCo, PBCO, MgCO, Hg,CO, Fes 4 8.2 x 10-12 5.2 x 10-12 1.5 x 10-15 1 x 10-15 NiS 1.3 x 10-22 Cos ZnS lodides Pbl, Agl…
- For a weak acid with a pKa of 6.0, calculate the ratio of conjugate base to acid at a pH of 5.0A base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 70 of the manganese has precipitated? Table 5-7 Solubility-Product Constants, K, at 25°C Fluorides Chromates (cont.) Ag, Cro, PbCro, Hydroxides (cont.) Ni(OH), Zn(OH), Cu(OH), Hg(OH)2 Sn(OH), Cr(OH), Al(OH), Fe(OH), Co(OH), Sulfides Baf, MGF2 PbF, SrF, CaF, 2.4 x 10-6 1.9 x 10-12 1.6 x 10-16 8 x 10-8 X 10-8 7.9 x 10-10 3.9 x 10-11 2 x 10-16 4.5 X 10-17 4 1.6 x 10-19 X 10-26 X 10-27 6.7 x 10-31 Carbonates NiCO, CaCO, BaCO, SrCO, CuCO, ZnCO, MNCO, FeCo, Ag,CO, CdCo, PbCO, M9CO, Hg,CO, 1.4 X 10-7 4.7 x 10-9 3. Chlorides 1.6 x 10-9 PbCl, AgCI Hg,Cl, х 10-33 X 10-38 2.5 x 10-43 1.6 x 10-5 X 10-10 2.5 x 10-10 2 x 10-1o 8.8 x 10-11 2.1 X 10-11 7 1.7 x 10-10 1.1 X 10-18 6. Bromides PbBr2 X 10-16 X 10-19 X 10-21 5 x 10-22 2.5 x 10-22 X 10-26 1.0 x 10-28 MnS 4.6 x 10-6 5.0 x 10-13 Fes 4. AgBr Hg,Br, 8.2 x 10-12 NiS Cos Zns 1.3 x 10-22 3 5.2 x 10-12 1.5 x 10-15 1 x 10-15 9.0 x 10-15…What is the pH of a 0.25 M solution of acetic acid, Ka = 1.8 x 105. What percentage of the acid is dissociated?
- Calculate the theoretical pH of a Tris buffer (pH 8.0) at 0 ºC. Assume that room temperature is 22 ºCYou need to prepare an acetate buffer of pH 5.43 from a 0.621 M acetic acid solution and a 2.95 M KOH solution. If you have 730 mL of the acetic acid solution, how many milliliters of the KOH solution do you need to add to make a buffer of pH 5.43? The pKa of acetic acid is 4.76. Be sure to use appropriate significant figures.Sketch a titration curve and the structures of the major ionic forms of glutamic acid that exist in solution at the noted parts of the titration curve. Refer to the fully pronated glutamic acid and the pKa.