For real gases calculate the correction less terms for a finite size of molecule in a container for pressure and volume and accommodate them in the ideal gas equation to get Vander Waal’s equation of state

Q: To derive the Maxwell relation, write the equation giving the total change of energy starting with…

A: In this question we have to derive the given Maxwell equation.

Q: de Or =?,) =? OP

A: According to Van der Waals equation, where P = pressure V = volume  n = moles  R = gas constant =…

Q: Which state variable(s) varies/vary in Charles' law? O moles pressure volume temperature

A: At constant pressure absolute pressure of gas is directly proportional to absolute temperature.

Q: Non-ideal behavior for a gas is most likely to be observed under conditions of a) high pressure and…

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Q: Calculate the molar volume of carbon dioxide gas at 100 degree Celsius and 10 atm pressure using the…

A: Soln

Q: A 0.513 mol sample of N,(g) initially at 298 K and 1.00 atm Molar heat capacity at constant Туре of…

A: Given that : Moles of N2=0.513 gTemperature=298 KPressure of N2 = 1.00 atmIncrease in…

Q: When is the fugacity equal to the partial pressure of a gas? Fugacity is equal to partial…

A: Fugacity  is representing the actual behavior of real gases which distinctly different from the…

Q: How to prove that the temperature (T) of an ideal gas law is a state function?

A: Thermodynamics is the branch of chemistry which deals with the study of heat and other forms of…

Q: How does the Maxwell- Boltzman plot explain why the reaction favors the reactant for an exothermic…

A: For any reaction to occur, some amount of energy is needed by the reactant to get activated and…

Q: 3. Derive the Joule - Thomson coefficient for virial equation of state in terms of volume expansion.

A: Interpretation -  Drive the Joule-Thomson coefficient for virial equation of state in terms of…

Q: (a) List two experimental conditions under which gases deviatefrom ideal behavior. (b) List two…

A: (a)The gases deviate from ideal gas law in the conditions when it remains unsuccessful to explain…

Q: A particular gas cylinder will explode if the pressure exceeds 14×103KPa.The cylinder has a capacity…

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Q: Calculate the final pressure of a sample of water vapor that expands reversibly and adiabatically…

A: I have given the answer in the explanation section. Hope you will understand that.

Q: Compute for the partial pressure of each gas in the mixture.

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Q: concerning S and  ΔS

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Q: Which state variable(s) is/are constant in Boyle's law? temperature O volume pressure O moles

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Q: Is it acceptable to consider gaseous hydrogen as an ideal gas if the pressure is at 10 atm. Please…

A: Ideal gases do not possess attractive or repulsive forces under normal pressure and temperature…

Q: v) Volume is inversely proportional to the... .at constant T and P. a) moles b) pressure c)…

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Q: Hot air balloons work by changing the density of the air within the balloon, which causes the…

A: The root mean square velocity (RMS value) is the square root of the mean square of the velocity of…

Q: Compare and contrast an ideal gas with a real gas. If ideal gases do not exist, why can we use them…

A: Ideal Gas:An ideal gas is defined as a gas that obeys the laws of gases at all pressures and…

Q: Sp), =?, =?, )p =7 T

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Q: van Deemter Equation.

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Q: Which of the following is true of internal pressure? The value of internal pressure is zero for…

A: Internal pressure is a measure of how the internal energy of a system changes when it expands or…

Q: Draw the Maxwell-Boltzmann Distribution curves for a sample of a gas at two different temperatures,…

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Q: Explain whether I mole of O, or steam (H-O vapor) has the higher pressure at a given T and V.…

A: 1 mole of oxygen has higher pressure than 1 mole steam.

Q: Given A ≡ U – TS, derive the corresponding Maxwell relation.

A: Introduction :  We have to derive Maxwell relation for A= U-TS

Q: Find the following values for the real gas equation (van der Waals).

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Q: e An ideal mono-atomic gas is confined in a cylinder with the help of a niston that can slide inside…

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Q: Consider a collection of N, rubidium-87 (rubidium is atomic number 37) atoms confined inside a cube…

A: Bose-Einstein condensation is a matter of state in which most of the particles (mainly Bosons)…

Q: At temperature equal to 0 K, the volume of an ideal gas equal to zero. This is

A: We know that ideal gas always follow ideal gas equation.,  i.e., PV = nRT P = pressure of given…

Q: At constant pressure, the volume of a fxed mass of an ideal gas is directly proportional to the…

A: It states that, for a given mass of an ideal gas at constant pressure, the volume is directly…

Q: What is the initial temperature (°C) of a system that has the pressure decreased by 10 times while…

A: The solution is as follows :

Q: 1. Internal energy's natural variables are entropy, S, and V. Mathematically, it can be written as…

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Q: Calculate Boyle temperature for nitrogen assuming van der Waals behavior

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Q: approaches infinity in the virial equation of state, a real As the gas will start to behave as an…

A: Please find your solution below : Virial equation of state is an equation that describes the…

Q: How to prove (mathematically) that the temperature of van der waals equation is a state function?

A: The van der Waal equation is    [P+((an^2​)/(v^2)][v−nb]=nRT   ∴  for every quantity, there is a…

Q: Jean-Baptiste-Andrè Dumas designed a simple method in determining the molar mass of an unknown…

A: In the Dumas method, the molecular mass of the gas can be determined by measuring the temperature,…

Q: Maryam was in conversation with Ghadeer and were discussing about how to measure the amount of…

A: An amount of energy is generated through pizza.

Q: One mole of an ideal gas undergoes the pressure–volume changes shown in following diagram. Starting…

A: The PV diagram given for the process is clockwise cycle as shown below.

Q: Why is the term that corrects for volume, negative and the term that corrects for pressure is…

A: The gaseous state is the state of matter with least intermolecular force of attraction between…

Q: Why is the term that corrects for volume, negative and the term that corrects for pressure is…

A: According to the ideal gas law, we assume that the there is no interactions between the molecules…

Q: When is the fugacity equal to the partial pressure of a gas? O Fugacity is equal to partial pressure…

A: Given : We have to explain whether fugacity is equal to partial pressure of gas.

Q: A sample of H2 gas has a pressure of 1.2 atm at 25°C. If the pressure has increased to 1.5 atm at…

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