For reactions carried out under standard-state conditions, the equation AG= AH- TAS becomes AG =H - TAS.Assuming AH and AS equation: are independent of temperature, one can derive the K2 AH T2-T1 In- K1 R where K and K2 are the equilibrium constants at T1 and T2, respectively. Given that at 25.0°C, K, is 4.63 x 103 for the reaction N204(g) 5 2NO2(g) AH = 58.0 kJ/mol calculate the equilibrium constant at 63.0°C. K =

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.18PAE: The reaction, 3 H2(g) + N2(g) (g), has the fol lowing equilibrium constants at the temperatures...
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For reactions çarried out under standard-state conditions, the equation AG= AH- TAS becomes
AG =H - TAS".
TAS .Assuming AH and AS
%3D
are independent of temperature, one can derive the
equation:
K2
In-
K1
AH
T2- T1.
%3D
R
where K and K2 are the equilibrium constants at T1 and T2, respectively. Given that at 25.0°C, K, is
4.63 x 10 for the reaction
N204g) 5 2NO28)
AH
= 58.0 kJ/mol
calculate the equilibrium constant at 63.0°C.
Kc
%3D
Transcribed Image Text:For reactions çarried out under standard-state conditions, the equation AG= AH- TAS becomes AG =H - TAS". TAS .Assuming AH and AS %3D are independent of temperature, one can derive the equation: K2 In- K1 AH T2- T1. %3D R where K and K2 are the equilibrium constants at T1 and T2, respectively. Given that at 25.0°C, K, is 4.63 x 10 for the reaction N204g) 5 2NO28) AH = 58.0 kJ/mol calculate the equilibrium constant at 63.0°C. Kc %3D
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