Draw the product of an SN2 reaction shown below. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers. Ignore inorganic byproducts. NaCN acetonitrile Br P
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- Dtermine the reagents that can accomplish the rxn CH2OH (1) Reagent ? (2) Reagent ? C9H1202 (4) Reagent ? (3) H+ a. (1) SOC12 (2) 1-propanol; (4) PCC/pyridine b. (1) NaH, (2) acetone, (4) NABH4 c. (1) NaH, (2) epoxide (4) PCC/pyridine d. (1) Jones reagent, (2) NaH, (4) epoxideDraw the major organic product of the reaction shown below. HO NazCr207 H2SO4, H20 H3C CH3 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. C opy aste ChemDoodleDraw the product of an SN2 reaction shown below. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers, Ignore inorganic byproducts. CH3I DMSO Drawing < + Li Atoms, Bonds and Rings Charges Draw or tap a new bond to see suggestions. Undo Drag To Pan Reset Remove Done ( +
- H :O: 819 -CI: :CI: This is an E2 anti elimination. b Draw the organic product of the mechanism step above. Draw POCI3 and its derivatives with a P=O double bond. • You do not have to consider stereochemistry. Ignore alkene stereochemistry. • Do not include counter-ions, e.g., Na+, I, in your answer. Sn [F Correct ChemDoodle"Draw the major organic product of the reaction shown below. -OH Ill You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. K₂Cr₂07 H₂SO4, H₂O Ⓡ Y - [ ]# 2 ChemDoodle 661. Indicate if each of the following reactions is likely to go through an SN1 or SN2 mechanism. Briefly justify your choice. a) H3C-1 b) c) Br te d) e) NaCl, H₂O NaCN Br KBr LiBr, DMSO H3C-Cl Br for Nal, CH3OH Br g) h) i) j) Br CH3OH OCH 3 NaI NaBr, DMSO OH-, H₂O OCH3 Br OH
- c. Snl reactions dominate under polar protic solvents. Increasing the polarity of the solvent will increase the rate of the reaction because the polar solvent will stabilize the dispersed charges on the transition state more than it will stabilize the neutral reactant. Label areas of ô* and & on the molecules of the transition state of the SN1 reaction below: Me Me Ме Me Me H20 Br -Br OH + НО \'H Et Et RDS Et H Et Et transition state not isolable carbocation intermediate not isolableOrganic chem 2 For the reaction: HCI 40° C a Draw the structure(s) of the major product(s) from addition of 1 equivalent of HX to the conjugated diene. • Only give structures deriving from the most stable carbocation. . You do not have to consider stereochemistry. ⚫ Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. อ २ [] ChemDoodle ་2. Propose electron-pushing arrows for each step of the radical mechanism shown below. PhO,s.-so,Ph jor for > H [w-o [w-o Pho2s-sO,Ph H
- Determine the major organic product for the reaction scheme shown. Br 1.2 Li, Et₂0 2. -C=CH 3. CH3(CH₂)2CI Select Draw / / || G Rings C H More Erase Q2 QDraw the major products of the SN1 reaction shown below. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers, where applicable. Ignore any inorganic byproducts. H OH HCI ✓Rank the substrates below in order of increasing reactivity (from slowest to fastest) in a substitution reaction with KCN in DMSO. (Tos = tosylate) %3D Br Br OTos 1 O 3< 1 < 2 O 1< 3 < 2 O 1< 2 < 3 O 3<2< 1 O 2 < 3 < 1 MacBook Pro 3. 2.