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Discuss 3 limitations of friedel crafts with the aid of suitable examples
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- Write suitable detailed mechanisms to account for the formation of the products in the following reactions, paying particular attention to clear drawings of structures and arrows as well as proper stoichiometry [WHERE APPROPRIATE]. You are required to show ALL intermediates and any by products that are formed in these reactions.Please give the three synthesis of tetrazines and tetrazole with mechanismDescribe the structure of the methylethium tetramer (including the orbitalsinvolved in the bonds) and indicate a reaction in which this compound isapplied.
- (b) acid, HNO3 to produce compound L. The reaction of compound L with bromine, Br2 in the presence of iron tribromide, FeBr3 produced compound M. Benzene also undergoes Fridel-crafts alkylation reaction with chloroethane, CH;CH2CI using catalyst N to produce compound P. Benzene, CeHe undergoes substitution reaction with concentrated nitric Benzena, CsHe menjalani tindak balas penukargantian dengan asid nitrik, HNO, pekat untuk menghasilkan sebatian L. Tindak balas sebatian L dengan bromin, Brz dengan kehadiran ferum tribromida, FeBrs menghasilkan sebatian M. Benzena juga menjalani tindak balas alkilasi Fridel-crafts dengan kloroetana, CH3CH2CI dengan menggunakan pemangkin N untuk menghasilkan sebatian P. (i) Draw the structural formula of L, M and P. Lukiskan formula struktur bagi sebatian L, M dan P. (ii) State catalyst N. Nyatakan pemangkin N. (iii) Show the formation of electrophile that will be reacted with benzene for the formation of compound P.In each of the following electrophilic substitution reactions (i) as a first step show the“preactivation” or generation of an electrophilic species; (ii) using arrows provide a mechanisticexplanation of the course of the reaction (show all resonance structures contributing for intermediatearenium ion stabilization); (iii) write all major products of the reaction. Friedel-Crafts acylation of anisole with 2-methylpropanoyl chloride ((CH3)2-CH-COCl) inthe presence of AlCl3 as a catalyst.the following reaction scheme leads to the formation of compound B. give the structure of the final products and of the intermediate product A and justify, using the mechanism, the formation of these
- a) Consider the reaction scheme below. -[•] PhLi HONH,, HCI A ELOH B D (i) Deduce the structures of compounds A, D and intermediate C. (ii) Outline the mechanism for the conversion of A to B.Observe and identify what's the general reaction scheme and explain it.What is the background on the chemistry of electrophilic aromatic substitution reactions, what is the importance of nitration reactions in organic synthesis, and the reactivity of methyl benzoate, a methyl ester of benzoic acid. With references
- V) Outline a synthesis of the following compound from benzene and other appropriate organic or inorganic reagents. ? CH3 ? CO2H Excess ?State the detailed reaction scheme and mechanism of the following reactionplease provide the missing organic materials starting materials, reagents/reactions, conditions or organic products in the reaction below. kindly provide and show ther eaction mechanism as well