Construct an approximate molecular orbital energy diagram for a hypothetical planar form of NH3. From a consideration of the atomic energy levels, place the N and H3 orbitals on either side of a molecular orbital energy-level diagram. Then use your judgement about the effect of bonding and anti bonding interactions and energies of the parent orbitals to construct the molecular orbital energy levels in the centre of your diagram and draw lines indicating the contributions of the atomic orbitals to each molecular orbital. Ionization energies are I(H1s) = 13.6 eV, I(N2s) = 26.0 eV, and I(N2p)=13.4 eV.

The molecular orbital is formed by the linear combination of atomic orbitals of the two…

Answered: Construct an approximate molecular…

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter1: Covalent Bonding And Shapes Of Molecules

Section: Chapter Questions

Problem 1.61P: Using cartoon representations, draw a molecular orbital mixing diagram for a CO bond. In your...

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Construct an approximate molecular orbital energy diagram for a hypothetical planar form of NH3.

From a consideration of the atomic energy levels, place the N and H3 orbitals on either side of a molecular orbital energy-level diagram. Then use your judgement about the effect of bonding and anti bonding interactions and energies of the parent orbitals to construct the molecular orbital energy levels in the centre of your diagram and draw lines indicating the contributions of the atomic orbitals to each molecular orbital. Ionization energies are I(H1s) = 13.6 eV, I(N2s) = 26.0 eV, and I(N2p)=13.4 eV.

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