Consider the -CH3 group and describe its directing properties in electrophilic aromatic substitution.The -CH3 is a metadirector because ofresonance away ortho/parametaresonance into the ginduction away from the ringO induction towards the ring

In the question it is asked about the electronic nature of methyl group that whether it has…

Consider the -CH3 group and describe its directing properties in electrophilic aromatic substitution. The -CH3 is a meta director because of O resonance away ortho/para meta resonance into th induction away from the ring O induction towards the ring

Consider the -CH3 group and describe its directing properties in electrophilic aromatic substitution. The -CH3 is a meta director because of O resonance away ortho/para meta resonance into th induction away from the ring O induction towards the ring

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter19: Eas: Electrophilic Aromatic Substitution

Section: Chapter Questions

Problem 7CTQ

See similar textbooks

Related questions

Q: Calculate the pOH of the following solutions at 25 degrees Celsius. 1 [H+] = 1.0 x 10^-7 M* 2 [H+]…

A: First of all we know that relation between pH and pOH is : pH + pOH = 14 Or. pOH = 14 -…

Q: Electrophilic bromination of an equimolar mixture of methylbenzene (toluene) and…

A: Aromatic compounds like benzene give electrophilic substitution reaction. If an electron donating…

Q: What is the functional group of the molecule below? ester aldehyde carboxylic acid ketone H3C C. CH3

Q: What is the energy change when the temperature of 12.2 grams of solid magnesium is decreased from…

Q: Consider the following chemical reaction: MgO (s) + 2HCl(aq) ---------->MgCl2(aq) + H2O(l) How…

Q: A sample of gas has the volume of 148 L. at the pressure of 102 mmHg. If the volume is changed…

A: Boyle's law: According to Boyle’s law, the absolute pressure exerted by a given mass of an ideal…

Q: Marked out of 1.00 Flag question Time left 0:49:41 pka of methanol is higher than pka of water due…

A: We know, pKa is a number that describes the acidity of a particular molecule. Higher the pKa…

Q: Which compound of each of the following pairs is the STRONGER BASE? * (A) (B) O Option A O Option B…

Q: a) Япон OH b) їх c) з-за 8-4 HO. d) e) я ОН xћ ОН НО ОН

A: Synthesis of given products from given starting materials is achieved by various reagents.

Q: To prepare a solution of NaCl, you weigh out 2.634 (+0.002) g and dissolve it in a volumetric flask…

A: Mass of NaCl = 2.634 +- 0.002 g Molar mass of NaCl = 58.443 +- 0.0012 g/mol Volume of solution =…

Q: What set of words best describes the side chain of the amino acid Histidine? *A) Non-polar,…

A: Here the question is about side chain of amino acid histidine. Given some characteristics of amino…

Q: 13. What is the final concentration of zinc oxide, as a percent concentration (w/w), when 15 g of…

A: First we need to find total amount of zinc-oxide in the mixture,and total weight of the mixture.…

Q: SO4 + NH*4 → NH3 + HSO 4 O NH*4, SO4 O NH3, HSO 4 O NH3, SO²4 tion below?

Q: Which of the following Newman projections correctly represents the structure of (2R,3S)-2-chloro-…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: Calculate the total volume, in milliliters, of clindamycin 600 mg/4 mL solution needed to prepare…

Q: 2. Find the instantaneous rate of reaction from the following data at time respectively 6 min and 10…

A: To find the instantaneous rate of reaction from the following data at time respectively 6 min and 10…

Q: Provide IUPAC names for the given structures or structures for the given names. HN-CH₂ CI god you

A: The answer to the following question is-

Q: Electrophilic bromination of an equimolar mixture of methylbenzene (toluene) and…

A: Electrophilic bromination of an equimolar mixture of methylbenzene (toluene) and…

Q: It takes 40 mL of 0.75 M NaOH solution to completely neutralize 150 mL of a sulfuric acid solution…

Q: Hydrogen peroxide decomposes to water and oxygen according to the reaction below: 2 H2O2(aq) → 2…

A: Solution: In the given question we have to calculate the average rate of disappearance in the first…

Q: (A) (B) SiO3²-or SO3²-

Q: Classify the salts according to Strength and Role in the Buffer Example Acid X: SA/conjugate acid…

Q: Which of the following is an effective way to complete the synthes below. O LNH, 2) H₂O* 1) HNOyH₂50…

Q: An aqueous glucose solution of unknown concentration is found to have a freezing point of -0.452oC.…

A: The formulae for the glucose is C₆H₁₂O₆ The freezing point of the glucose solution = Tf = -0.452°C…

Q: 1. Which of the following statements regarding the purification of organic compounds is TRUE? a.…

A: Recrystallization: In this method of purification,a solid is dissolved it in a hot solvent and then…

Q: 9. Provide the major dehydration product of the following reaction. Recall which of the four…

Q: 20. Draw the full acetal formation scheme on your paper, and then draw in the curved arrows for each…

A: Acetals are geminal-diether derivatives of aldehydes, formed by reaction with excess amount of an…

Q: Draw structural formulas for the diene and dienophile that combine in a Diels-Alder reaction to form…

A: The above reaction is proceed by specific mechanism as shown below.

Q: Liquid octane (CHa (LH2)6 CH.) will react with gaseous oxygen (0)) to produce gaseous carbon dioxide…

Q: In the molecule below which is the alpha carbon OF OD HA D

Q: What is the functional group of the product of the reaction below? H3 C H2 ether ketone carboxylic…

Q: Calculate the percent dissociation of the acid in each of the following solutions a. 0.50 M acetic…

Q: 8. CH₁ CH, 13 H C=C H

Q: Which compound of each of the following pairs is the STRONGER ACID? (A) (B) O Option A O Option B…

A: Given, Which compound of each of the following pairs is the stronger acid, A) H2SO4 or B) H2SO3…

Q: A. If an element with the valence configuration 4s23d7 loses 3 electron(s), these electron(s) would…

Q: What is the I.U.P.A.C. name of the following compound? CH₂CH3 CH₂CHCH₂CH₂ 2-ethylbutane…

A: Rules for nomenclature of alkanes- Select and name the longest continuous carbon chain Identify…

Q: What is the molar solubility of Pb(103)2 in 0.1295 M Pb(NO3)2? The solubility reaction is…

A: Recall the data, molar solubility of Pb(NO3)2=0.1295M Ksp of Pb(IO3)2=2.57*10-13 molar solubility of…

Q: QUESTION 8 What is the major product of the following reaction? 00. of CHCH₂ B CHCH₂ D

Q: Draw structures in blank boxes to complete the following reactions. me O₂N mhong Mallo H₂N CI سعد by…

A: Carbocylic acid derivatives undergo nucleophilic substitution reactions

Q: The value of Ka for acetic acid is 1.75 × 10—5. The pH of a 0.100 M solution of acetic acid is:

Q: The graph shows the molecular speed of four gases at 27 °C. What, if any, relationship is observed…

A: Most probable speed (Vmp) is defined as the speed acquired by most of the molecules of the gas. From…

Q: Part 2: Assay of tartaric acid (Jenkin's Quantitative Pharmaceutical Chemistry by Knevel, pp.108)…

Q: Infrared spectrum " (the right one) represents which of the following compounds/Notice the labels…

A: Given that, the IR spectrum. From the given IR spectrums, we have to determine the spectra ii…

Q: A sample of kyrpton gas occupies a volume of 8.14 L at 46.0 degrees Celsius and 0.540 atm. If it is…

A: We solve this problem by using gas equation PV=nRT Where P= pressure V= volume n= mole R= gas…

Q: A buffer is prepared containing 1.00 M acetic acid and 1.00 M sodium acetate. What is its pH? The Ka…

Q: A 10 ml of concentrated acetic acid was added in a sufficient quantity of water to make 350 ml of…

A: Since you have asked a question with multiple sub-parts, as per our company guidelines we are…

Q: Of the structures shown, which two are isomers? 1 and 2 1 and 3 O 1 and 4 2 and 4 O 3 and 4 2

A: Compounds that have same formula(same numbers of atom) but a different arrangement of atoms in the…

Q: 20:24 : E) 03 12. Fill in the box with the major organic product of the first step of the reaction…

Q: 1. Find the absolute and percent relative uncertainty. 6.2 (10.2) -4.1 (±0.1) = ? a. b. 9.43 (±0.05)…

A: To find the absolute and percent relative uncertainty. a. 6.2 (±0.2)- 4.1 (±0.1)=?b. 9.43 (±0.05) x…

Q: What is the answer in KJ?

A: The enthalpy change for the required reaction : 2C2H4(g) + H2(g)→ C4H10(g) is - 230.2 KJ.

Question

Consider the -CH3 group and describe its directing properties in electrophilic aromatic substitution.
The -CH3 is a meta
director because of
resonance away ortho/para
meta
resonance into the g
induction away from the ring
O induction towards the ring

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Selection Rules for Pericyclic Reactions

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Identify the ring which is more reactive towards electrophilic aromatic substitution.
Arrange these compounds in order of reactivity towards electrophilic aromaticsubstitution, with the most reactive compound listed first
How would we know using aromatic vicinal coupling that the c-c bond was formed between compound B and C to for the product A? (HO)₂B. Br ------ compound A compound B compound C
Draw a detailed mechanism for the FeBr3@catalyzed reaction of ethylbenzene with bromine, and show why the sigma complex (and the transition state leading to it) is lower in energy for substitution at the ortho and para positions than it is for substitution at the meta position.
Provide the complete mechanism using curved arrow formalism for the reaction of p-isopropxlbenzoic acid undergoing nitration. Tell how many peaks in the 'H and 13C NMR spectrum that would be observed for the final product.
The bicyclic heterocycles quinoline and indole undergo electrophilic aromatic substitution to give the products shown.(a) Explain why electrophilic substitution occurs on the ring without theN atom for quinoline, but occurs on the ring with the N atom in indole. (b)Explain why electrophilic substitution occurs more readily at C8 than C7in quinoline. (c) Explain why electrophilic substitution occurs morereadily at C3 rather than C2 of indole.
1) Explain why electrophilic aromatic substitution in Pyrrole takes place at C-2 positions whereas, in Pyridine it takes place at C-3 position? 2) LDA is the base of choice for carbonyl compound to completely convert into enolate. Why? 3) List the following esters in order of decreasing reactivities towards hydrolysis with reason:Methyl benzoate, p-cyano methyl benzoate and p-hydroxy methyl benzoate
Bromide Bhas normal activity (for a secondary bromide) towards SN1 substitution, but A has much higher reactivity and Chas much lower reactivity.
How is benzophenone suited for nueleophilie aromatic Sub Stitution which positions and the ring can be Substituteb
Draw the structures of compounds A and B in the scheme below. Be sure to indicate the stereochemistry. E2 Ph El
(c) Nitrobenzene will undergo electrophilic aromatic substitution at meta position, but not at the ortho and para positions. Explain by showing all the resonance structures involved.
During electrophilic aromatic substitution, a resonance-stabilized cation intermediate is formed, Groups, already present on the benzene ring, that direct ortho/para further stabilize this intermediate by participating in the resonance delocalization of the positive charge. resonance Assume that the following group is present on a benzene ring at position 1 and that you are brominating the ring at positon 4. In the box below draw the structure of the rese contributor that shows this group actively participating in the charge delocalization. H₂C • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading.