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- a) Give the molecular formula and draw the skeletal structure for 3-bromo-3- methylhexane. b) Name (including E/Z stereochemistry) the FIVE alkenes that can produce 3-bromo-3- methylhexane on reaction with HBr. Draw the skeletal structure of each molecule.??? c) Define the type of stereoisomerism present in 3-bromo-3-methylhexane. Name and draw the tetrahedral representation of the two stereoisomers?. d) For the base-catalysed hydrolysis of 3-bromo-3-methylhexane (i.e. reaction with the nucleophile OH-): i) ii) iii) iv) State whether the reaction is likely to proceed by an SN1 or SN2 mechanism, and explain your choice Give the likely rate law for the reaction. Explain your choice. For the reaction intermediate, draw its structure and give the VSEPR description of the geometry at the reaction centre Give the names and draw the structures of the two reaction products. Explain your conclusions10) For the reaction between isopropyl 1-propyl (or 'n-propyl') ether and HBr, which type of reaction best matches the expected products? A) Acid-catalyzed dehydration B) Nucleophilic substitution reaction C) Ether cleavage reaction D) Nucleophilic addition-elimination reaction1. Write in the correct reagents to accomplish these reactions. a) 2-methyl-2-pentanol b) CH3CH2CH₂OH → 2-chloro-2-methylpentane CH3CH₂CH
- 1-Draw the structure and write the IUPAC name of celecoxib 2- Draw the structure of organic compound (O-cresol) Name and Draw the structures of all possible chemical (Electrophilic aromatic substitution) reactions of the compound namely; Halogenation (Chlorination or Bromination) Nitration Sulphonation Friedal Craft Alkylation Friedal Craft Acylation1. Draw structural formulas for 1-bromobutane, 2-bromobutane, 2-bromo-2- methylpropane, 1-bromo-2-methylpropane, and 1-bromo-2,2-dimethylpropane. Classify each compound as a primary halide, secondary halide, or tertiary halide. 2. Draw structural formulas for acetone and ethanol. Which solvent is more polar? Explain. 3. A student wishes to determine the rate law for the reaction A +B → C. The student doubles the concentration of A while holding the concentration of B constant and finds that the rate of the reaction doubles. The student then doubles the concentration of B while holding the concentration of A constant and finds that the rate is unchanged. Write the rate law for this reaction. (Refer to a general chemistry text, if necessary.) Experimental Procedure S aA) An Alcohol X has the structure of (CH,), C(OH)CH(CH,),. i) State the IUPAC name of alcohol X. i) Outline the mechanism for the reaction occurring when alcohol X is converted into 2,3-dimethylbut-2-ene in the presence of a strong acid. i) Name the reaction in part ii). iv) Draw the structure and state the IUPAC name of an isomer of 2,3-dimethyl-2- butene which is also formed in the reaction. v) Explain why two products are obtained. vi) Write an equation for the reaction between alcohol X and ethanoyl chloride. vii) Outline a mechanism for this reaction, using ROH to represent the alcohol in the mechanism.
- 3. Complete the chemical equations for the following reactions. Draw the structure (condensed structural formulas) for the dominant product and write the names of the reactants and products (organic compounds only.) d) CHy Name reactant: Name product: e) CH=C-CH + 2 HBr 4-Cて。 Name reactant: Name product:1. Write a reaction showing how the compound ethanoic propanoic anhydride is prepared. Draw and name all constituional isomers of a compound having the molecular formula C4H&O2. 2.2. The molecules shown below are four terpineol isomers. They are isolated from plants and have distinct aromas. For example, a -terpineol is a common perfume ingredient and smells similar to lilacs. Hol H-O- a-terpineol B-terpineol Y-terpineol 4-terpineol A) Draw a structural isomer of terpineol that meet the following criteria. You should draw one unique structure for each set. You must draw each molecule twice, once as a skeletal structure and once as a complete Lewis structure showing all atoms, bonds, and lone pairs of electrons. i. Does not have a ring. ii. Has an E alkene. iii. Has a secondary alcohol. iv. Does not contain an alcohol. B) Draw a complete Lewis structure of a-terpineol showing all bonds, atoms and lone pairs of electrons.
- A certain hydrocarbon had the molecular formula C18H30 and contained two triple bonds. Ozonolysis gave CH₂(CH₂)CO₂H and HO₂CCH₂CH₂CO₂H as the only products. Draw a reasonable structure for this hydrocarbon. Click and drag to start drawing a structure.Industiral Chemistry Both Tetraethyl lead and methyl-t-butyl ether have been removed from or in the process of being removed from the gasoline additive industry. Explain why each of these compounds were used so highly, and why each is considered dangerous.Provide the classification (alcohol or ether) and provide the correct IUPAC name of each molecule. CH3 H3C. ОН b) Namena 1a) Classification: CH3 H3C. b) Namena 2a) Classification: CH3 H3C CH3 b) Nameina 3a) Classification: CH3 H3C он b) Namena 4a) Classification: CI H3C. CH3 OH ÓH CI b) Namena 5a) Classification: