Answer Questions #27 through #31 about the titration curves below (labeled a and b) for two different bases. The titrant acid used in both cases was 0.100M HCI and the volume of the base solutions in both cases was 75.0 mL mL. 14 14 12- 12- 10- 10- 8. 8- 6- 6- 4- 4- 2- 2- 20 40 60 80 100 0. 20 40 60 80 100 (а) Volume of acid added (mL) (b) Volume of acid added (mL) 0 Pon 27. In both of these titrations, what are you titrating with the HCl solution? A) Both are strong bases. B) Both C) Base in (a) is strong; base in (b) is weak. D) Base in (a) is weak; base in (b) is strong. weak bases. Hd Hd

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Chapter9: Acids, Bases, And Salts
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Problem 9.102E
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Answer Questions #27 through #31 about the titration curves below (labeled a and b) for two different
bases. The titrant acid used in both cases was 0.100M HCI and the volume of the base solutions in both
cases was 75.0 mL mL.
14
14
12
12 -
10
10-
8-
8-
6-
6-
4-
4-
2-
2-
0-
20
40
60
80
100
20
40
60
80
100
(a)
Volume of acid added (mL)
Volume of acid added (mL)
(b)
27. In both of these titrations, what are you titrating with the HCl solution?
A) Both are strong bases.
B) Both are weak bases.
C) Base in (a) is strong; base in (b) is weak.
D) Base in (a) is weak; base in (b) is strong.
28. Which of the two titrations has a base solution that is more concentrated?
A) (a)
B) (b)
C) Both (a) and (b) are the same concentration
D) It is impossible to say without knowing the exact K, values of the two bases.
E) Titrating with HCl won't work. You need to use another acid in the titration.
29. Which titration has the stronger base (larger K value)? Be careful: Make sure you compare the Kh values of
the bases, not the Ka values of the conjugate acids. Also, don't forget the relationship between Kb and pKb.
A) (a)
Hd
на
Transcribed Image Text:Answer Questions #27 through #31 about the titration curves below (labeled a and b) for two different bases. The titrant acid used in both cases was 0.100M HCI and the volume of the base solutions in both cases was 75.0 mL mL. 14 14 12 12 - 10 10- 8- 8- 6- 6- 4- 4- 2- 2- 0- 20 40 60 80 100 20 40 60 80 100 (a) Volume of acid added (mL) Volume of acid added (mL) (b) 27. In both of these titrations, what are you titrating with the HCl solution? A) Both are strong bases. B) Both are weak bases. C) Base in (a) is strong; base in (b) is weak. D) Base in (a) is weak; base in (b) is strong. 28. Which of the two titrations has a base solution that is more concentrated? A) (a) B) (b) C) Both (a) and (b) are the same concentration D) It is impossible to say without knowing the exact K, values of the two bases. E) Titrating with HCl won't work. You need to use another acid in the titration. 29. Which titration has the stronger base (larger K value)? Be careful: Make sure you compare the Kh values of the bases, not the Ka values of the conjugate acids. Also, don't forget the relationship between Kb and pKb. A) (a) Hd на
28. Which of the two titrations has a base solution that is more concentrated?
A) (a)
B) (b)
C) Both (a) and (b) are the same concentration
D) It is impossible to say without knowing the exact Kp values of the two bases.
E) Titrating with HCl won't work. You need to use another acid in the titration.
29. Which titration has the stronger base (larger Kp value)? Be careful: Make sure you compare the Kp values of
the bases, not the Ka values of the conjugate acids. Also, don't forget the relationship between Kb and pKb.
A) (a)
B) (b)
C) Both (a) and (b) are the same pKb.
D) It is impossible to say without knowing the exact Kp values of the two bases.
E) Titrating with HCl won't work. You need to use another acid in the titration.
30. Could the base titrated in (b) be used as part of a buffer? If so, what pH could be maintained by this buffer?
A) Yes, pH = 10
B) Yes, pH = 8
C) Yes, pH = 5
D) No
E) It is impossible to say because the titration curve is for a strong base.
31. Choose an indicator from the table on p. 817 of your textbook that would be suitable to signal the
equivalence point of titration (b).
A) crystal violet
B) bromphenol blue
C) phenol red
D) phenolphthalein
E) alizarin yellow R
Transcribed Image Text:28. Which of the two titrations has a base solution that is more concentrated? A) (a) B) (b) C) Both (a) and (b) are the same concentration D) It is impossible to say without knowing the exact Kp values of the two bases. E) Titrating with HCl won't work. You need to use another acid in the titration. 29. Which titration has the stronger base (larger Kp value)? Be careful: Make sure you compare the Kp values of the bases, not the Ka values of the conjugate acids. Also, don't forget the relationship between Kb and pKb. A) (a) B) (b) C) Both (a) and (b) are the same pKb. D) It is impossible to say without knowing the exact Kp values of the two bases. E) Titrating with HCl won't work. You need to use another acid in the titration. 30. Could the base titrated in (b) be used as part of a buffer? If so, what pH could be maintained by this buffer? A) Yes, pH = 10 B) Yes, pH = 8 C) Yes, pH = 5 D) No E) It is impossible to say because the titration curve is for a strong base. 31. Choose an indicator from the table on p. 817 of your textbook that would be suitable to signal the equivalence point of titration (b). A) crystal violet B) bromphenol blue C) phenol red D) phenolphthalein E) alizarin yellow R
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