-1An acidic liquid has a broad band at 3300 cm anda sharp band at 1710 cm-¹ in the infrared spectrum.One mole of this unknown reacts with one mole ofNaOH. The ¹H NMR spectrum shows threepeaks in the ratio 2 : 2:1. Microanalysis gave C,33.2%; H, 4.6%; C1, 32.7 %.Part ADeduce the structure of the unknown.Spell out the full name of the compound. The reaction of an unknown with ethanol in the presenceof a small amount of H₂SO4 leads to a compound thatsmells distinctly like rum. The protondecoupled ¹³CNMR spectrum of the product is as shown in the figure(* =solvent). (Figure 1)Figure200180 160 1401201008060401 of 120 ppm▼Part AWhat is the structure of the unknown ?Spell out the full name of the compound.Submit Request AnswerPart BWhat other structure(s) would be consistent with this ¹3C NMR spectrum?Enter your answers separated by a comma.

"Since you have asked multiple questions, we will solve the first question for you. If you want any…

An acidic liquid has a broad band at 3300 cm and a sharp band at 1710 cm-¹ in the infrared spectrum. One mole of this unknown reacts with one mole of NaOH. The ¹H NMR spectrum shows three peaks in the ratio 2:2: 1. Microanalysis gave C, 33.2 %; H, 4.6 %; C1, 32.7 %.

An acidic liquid has a broad band at 3300 cm and a sharp band at 1710 cm-¹ in the infrared spectrum. One mole of this unknown reacts with one mole of NaOH. The ¹H NMR spectrum shows three peaks in the ratio 2:2: 1. Microanalysis gave C, 33.2 %; H, 4.6 %; C1, 32.7 %.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy

Section12.SE: Something Extra

Problem 15AP: Write molecular formulas for compounds that show the following molecular ions in their...

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Concept explainers

UV Visible Spectroscopy

Spectroscopy refers to the absorption or emission of light or other radiations by matter. When a substance or chemical absorbs light or radiation, they reach an excited state followed by de-excitation or emission of the light or radiation forming distinct spectra. UV-visible spectroscopy or ultraviolet-visible refers to the absorption and emission in the ultraviolet and visible regions of the electromagnetic spectrum.

Question

-1
An acidic liquid has a broad band at 3300 cm and
a sharp band at 1710 cm-¹ in the infrared spectrum.
One mole of this unknown reacts with one mole of
NaOH. The ¹H NMR spectrum shows three
peaks in the ratio 2 : 2:1. Microanalysis gave C,
33.2%; H, 4.6%; C1, 32.7 %.
Part A
Deduce the structure of the unknown.
Spell out the full name of the compound.

The reaction of an unknown with ethanol in the presence
of a small amount of H₂SO4 leads to a compound that
smells distinctly like rum. The protondecoupled ¹³C
NMR spectrum of the product is as shown in the figure
(* =solvent). (Figure 1)
Figure
200
180 160 140
120
100
80
60
40
1 of 1
20 ppm
▼
Part A
What is the structure of the unknown ?
Spell out the full name of the compound.
Submit Request Answer
Part B
What other structure(s) would be consistent with this ¹3C NMR spectrum?
Enter your answers separated by a comma.

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