Active chlorine (CI)” is used both in water treatment and for cleaning. If it is in the water for babies; the added hypochlorite solution has a mass concentration of 0.4 mg/L; in solutions for cleaning vegetables, the concentration is 4 mg/L; for cleaning utensils is 8 mg/L and as a cleaning product, known as semitary water, the concentration is between 25 and 50 gL” Active chlorine (Ch. PM. 71.0 g/mol) can be determined through the following reactions below: A bleach sample (d = 1.04 g/mL) was prepared by diluting 25.0 mL of the sample into a 100 mL flask. The volume was completed with distilled water, 10.0 mL was pipetted, excess KI solution in acidic medium and titrated with S,0;” 0.158 mol/L. The average volume for three replicates was 16.2 mL. Based on these data answer: a) What is the average concentration of Cl2 (% m/m) for a sample of bleach? b) What is the volume of this sample that must be added to distilled water to prepare 50 liters of a vegetable cleaning solution?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.103QE
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“Active chlorine (CI)” is used both in water treatment and for cleaning. If it is in the water for babies; the added hypochlorite solution has a mass concentration of 0.4 mg/L; in solutions for cleaning vegetables, the concentration is 4 mg/L; for cleaning utensils is 8 mg/L and as a cleaning product, known as semitary water, the concentration is between 25 and 50 gL”
Active chlorine (Ch. PM. 71.0 g/mol) can be determined through the following reactions below:

A bleach sample (d = 1.04 g/mL) was prepared by diluting 25.0 mL of the sample into a 100 mL flask. The volume was completed with distilled water, 10.0 mL was pipetted,
excess KI solution in acidic medium and titrated with S,0;” 0.158 mol/L. The average volume for three replicates was 16.2 mL. Based on these data answer:

a) What is the average concentration of Cl2 (% m/m) for a sample of bleach?
b) What is the volume of this sample that must be added to distilled water to prepare 50 liters of a vegetable cleaning solution?

OC (aq)
OCI (aq) + 21 (aq) + 2H+ (aq)
+ 2H+ (aq)
+ Cl(aq)
→ Cl2(aq) + H₂O (1)
12 (aq) + Cl(aq) + H₂O (1)
2 S₂03² (aq) + 12 (aq) → S406² (aq) + 21 (aq)
Transcribed Image Text:OC (aq) OCI (aq) + 21 (aq) + 2H+ (aq) + 2H+ (aq) + Cl(aq) → Cl2(aq) + H₂O (1) 12 (aq) + Cl(aq) + H₂O (1) 2 S₂03² (aq) + 12 (aq) → S406² (aq) + 21 (aq)
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