A student investigates various properties of silver compounds in the lab. First, the student carries out the following procedure to determine the concentration of Ag* (aq) in a solution of AgNO3 (aq). The student adds an excess of 2.0 M HC1(aq) to 300.0 mL of the solution, causing AgCl(s) to precipitate. The precipitate is separated from the solution by filtering it through a pre-weighed piece of filter paper. The precipitate and filter paper are rinsed with distilled water, dried, and weighed. The data from the experiment are given in the table below. Initial mass of filter paper 0.650 g Mass of filter paper + A£CI(a) precipitate after drying 0.793 g (a) Calculate the number of moles of AgCl(s) that precipitated. (The molar mass of AgCl is 143 g/mol). Please respond on separate paper, following directions from your teacher. (b) Assuming that all of the Ag* (aq) ions precipitated, calculate the original molarity of Ag* (aq) in the solution before HCI(aq) was added. Please respond on separate paper, following directions from your teacher. (e) The calculated concentration of Ag* (aq) from the student's data is lower than the actual concentration of the original solution. The student claims that the calculated concentration is too low because some of the AgCl(s) passed through the filter paper. Do you agree or disagree? Justify your answer. Please respond on separate paper, following directions from your teacher. After the experiment, the student learns that the precipitate, AgCI(s), is slightly soluble in water. To determine the solubility, the student mixes a sample of the precipitate with warm, distilled water to make a saturated solution. The student finds the following equation for the dissolution of AgCl(a) in

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12:42
Schoology
1 /4 >
O 157% O
A student investigates various properties of silver compounds in the lab. First, the student carries out
the following procedure to determine the concentration of Ag* (aq) in a solution of AgNO3(aq). The
student adds an excess of 2.0 M HCl(aq) to 300.0 mL of the solution, causing AgCl(8) to precipitate.
The precipitate is separated from the solution by filtering it through a pre-weighed piece of filter paper.
The precipitate and filter paper are rinsed with distilled water, dried, and weighed. The data from the
experiment are given in the table below.
Initial mass of filter paper
0.650 g
Mass of filter paper + AgCl(s) precipitate after drying
0.793 g
(a) Calculate the number of moles of AgCl(s) that precipitated. (The molar mass of AgCl is
143 g/mol).
O Please respond on separate paper, following directions from your teacher.
(b) Assuming that all of the Ag* (aq) ions precipitated, calculate the original molarity of Ag* (aq) in
the solution before HCl(aq) was added.
O Please respond on separate paper, following directions from your teacher.
(c) The calculated concentration of Ag+ (ag) from the student's data is lower than the actual
concentration of the original solution. The student claims that the calculated concentration is too low
because some of the AgCl(s) passed through the filter paper. Do you agree or disagree? Justify your
answer.
O Please respond on separate paper, following directions from your teacher.
After the experiment, the student learns that the precipitate, AgCl(s), is slightly soluble in water. To
determine the solubility, the student mixes a sample of the precipitate with warm, distilled water to
make a saturated solution. The student finds the following equation for the dissolution of AgCl(s) in
Capyrighe 201. The Cullepe nd. These mterials we pan of a Colu unl prgrm. Uor disikien of thee mrials oline in pri heyand yor
whel's paticipwien in the pogrm i prohibted
Page 1 of 9
AP OCollegolloard
AP Chemistry
Test Booklet
Final
water and a Kap value at the temperature of the water.
AgCl(s) 2 Ag*(aq) + Cl¯(aq)
K, = 9.0 x 10–10
(d) Calculate [Ag+] in the student's solution.
O Please respond on separate paper, following directions from your teacher.
(e) The value of Kp of another silver salt, AgF(s), is 2.0 × 10². If separate, saturated solutions of
AgF(8) and AgCI(s) are prepared, which solution will have the greater [Ag*]? Justify your answer.
O Please respond on separate paper, following directions from your teacher.
(f) The student finds the following particulate model of AgCl(s). Assuming the crystal structures are
similar, how should the student modify the model to represent AgF(s)? Justify your answer in terms of
the radius and arrangement of electrons in the ions.
Ag*
Ag+
Ag+
Ag+
CF
Transcribed Image Text:12:42 Schoology 1 /4 > O 157% O A student investigates various properties of silver compounds in the lab. First, the student carries out the following procedure to determine the concentration of Ag* (aq) in a solution of AgNO3(aq). The student adds an excess of 2.0 M HCl(aq) to 300.0 mL of the solution, causing AgCl(8) to precipitate. The precipitate is separated from the solution by filtering it through a pre-weighed piece of filter paper. The precipitate and filter paper are rinsed with distilled water, dried, and weighed. The data from the experiment are given in the table below. Initial mass of filter paper 0.650 g Mass of filter paper + AgCl(s) precipitate after drying 0.793 g (a) Calculate the number of moles of AgCl(s) that precipitated. (The molar mass of AgCl is 143 g/mol). O Please respond on separate paper, following directions from your teacher. (b) Assuming that all of the Ag* (aq) ions precipitated, calculate the original molarity of Ag* (aq) in the solution before HCl(aq) was added. O Please respond on separate paper, following directions from your teacher. (c) The calculated concentration of Ag+ (ag) from the student's data is lower than the actual concentration of the original solution. The student claims that the calculated concentration is too low because some of the AgCl(s) passed through the filter paper. Do you agree or disagree? Justify your answer. O Please respond on separate paper, following directions from your teacher. After the experiment, the student learns that the precipitate, AgCl(s), is slightly soluble in water. To determine the solubility, the student mixes a sample of the precipitate with warm, distilled water to make a saturated solution. The student finds the following equation for the dissolution of AgCl(s) in Capyrighe 201. The Cullepe nd. These mterials we pan of a Colu unl prgrm. Uor disikien of thee mrials oline in pri heyand yor whel's paticipwien in the pogrm i prohibted Page 1 of 9 AP OCollegolloard AP Chemistry Test Booklet Final water and a Kap value at the temperature of the water. AgCl(s) 2 Ag*(aq) + Cl¯(aq) K, = 9.0 x 10–10 (d) Calculate [Ag+] in the student's solution. O Please respond on separate paper, following directions from your teacher. (e) The value of Kp of another silver salt, AgF(s), is 2.0 × 10². If separate, saturated solutions of AgF(8) and AgCI(s) are prepared, which solution will have the greater [Ag*]? Justify your answer. O Please respond on separate paper, following directions from your teacher. (f) The student finds the following particulate model of AgCl(s). Assuming the crystal structures are similar, how should the student modify the model to represent AgF(s)? Justify your answer in terms of the radius and arrangement of electrons in the ions. Ag* Ag+ Ag+ Ag+ CF
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