(a) Differentiate the stretching frequencies of CO between two isomers of Co(CO);Cl2(PPh3) in their infrared spectroscopy. (b) Compare and contrast the signals of the following characterization techniques for two isomers of Rh(CO),H2 complex: (i) 'H and 1°C nuclear magnetic resonance (NMR) (ii) infrared spectroscopy

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Kindly answer question a & b

(a)
Differentiate the stretching frequencies of CÓ between two isomers of
Co(CO);Cl2(PPH3) in their infrared spectroscopy.
(b)
Compare and contrast the signals of the following characterization
techniques for two isomers of Rh(CO)4H2 complex:
(i)
'H and 1°C nuclear magnetic resonance (NMR)
(ii)
infrared spectroscopy
(c)
By giving an appropriate example, describe the metal-metal (M-M) bond
lengths/distances when monodentate and bidentate ligands are
introduced to a complex in different substitution reactions.
Transcribed Image Text:(a) Differentiate the stretching frequencies of CÓ between two isomers of Co(CO);Cl2(PPH3) in their infrared spectroscopy. (b) Compare and contrast the signals of the following characterization techniques for two isomers of Rh(CO)4H2 complex: (i) 'H and 1°C nuclear magnetic resonance (NMR) (ii) infrared spectroscopy (c) By giving an appropriate example, describe the metal-metal (M-M) bond lengths/distances when monodentate and bidentate ligands are introduced to a complex in different substitution reactions.
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